Design of an alternate antibody fragment format that can be produced in the cytoplasm of Escherichia coli.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
30 08 2023
Historique:
received: 23 05 2023
accepted: 28 08 2023
medline: 1 9 2023
pubmed: 31 8 2023
entrez: 30 8 2023
Statut: epublish

Résumé

With increased accessibility and tissue penetration, smaller antibody formats such as antibody fragments (Fab) and single chain variable fragments (scFv) show potential as effective and low-cost choices to full-length antibodies. These formats derived from the modular architecture of antibodies could prove to be game changers for certain therapeutic and diagnostic applications. Microbial hosts have shown tremendous promise as production hosts for antibody fragment formats. However, low target protein yields coupled with the complexity of protein folding result in production limitations. Here, we report an alternative antibody fragment format 'Fab

Identifiants

pubmed: 37648872
doi: 10.1038/s41598-023-41525-3
pii: 10.1038/s41598-023-41525-3
pmc: PMC10469194
doi:

Substances chimiques

Immunoglobulin G 0
Single-Chain Antibodies 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

14188

Informations de copyright

© 2023. Springer Nature Limited.

Références

Rettenbacher, L. A. et al. Microbial protein cell factories fight back?. Trends Biotechnol. 40, 576–590 (2022).
doi: 10.1016/j.tibtech.2021.10.003
Alibakhshi, A. et al. Targeted cancer therapy through antibody fragments-decorated nanomedicines. J. Control. Release 268, 323–334 (2017).
pubmed: 29107128 doi: 10.1016/j.jconrel.2017.10.036
Chen, H. et al. Strategies and applications of antigen-binding fragment (Fab) production in Escherichia coli. Pharm. Front. 03, e39–e49 (2021).
doi: 10.1055/s-0041-1735145
Kang, T. H. & Seong, B. L. Solubility, stability, and avidity of recombinant antibody fragments expressed in microorganisms. Front. Microbiol. 11, 1–10 (2020).
doi: 10.3389/fmicb.2020.01927
Nelson, A. L. Antibody fragments: Hope and hype. MAbs 2, 77–83 (2010).
pubmed: 20093855 pmcid: 2828581 doi: 10.4161/mabs.2.1.10786
Walsh, G. & Walsh, E. Biopharmaceutical benchmarks 2022. Nat. Biotechnol. 40, 1722–1760 (2022).
pubmed: 36471135 pmcid: 9735008 doi: 10.1038/s41587-022-01582-x
Sandomenico, A., Sivaccumar, J. P. & Ruvo, M. Evolution of Escherichia coli expression system in producing antibody recombinant fragments. Int. J. Mol. Sci. 21, 1–39 (2020).
doi: 10.3390/ijms21176324
Gani, K., Bhambure, R., Deulgaonkar, P., Mehta, D. & Kamble, M. Understanding unfolding and refolding of the antibody fragment (Fab). I. In-vitro study. Biochem. Eng. J. 164, 107764 (2020).
doi: 10.1016/j.bej.2020.107764
Lee, Y. K., Brewer, J. W., Hellman, R. & Hendershot, L. M. BiP and immunoglobulin light chain cooperate to control the folding of heavy chain and ensure the fidelity of immunoglobulin assembly. Mol. Biol. Cell 10, 2209–2219 (1999).
pubmed: 10397760 pmcid: 25436 doi: 10.1091/mbc.10.7.2209
Feige, M. J. et al. An unfolded CH1 domain controls the assembly and secretion of IgG antibodies. Mol. Cell 34, 569–579 (2009).
pubmed: 19524537 pmcid: 2908990 doi: 10.1016/j.molcel.2009.04.028
Humphreys, D. P. et al. A plasmid system for optimization of Fab′ production in Escherichia coli: Importance of balance of heavy chain and light chain synthesis. Protein Expr. Purif. 26, 309–320 (2002).
pubmed: 12406686 doi: 10.1016/S1046-5928(02)00543-0
Mehta, D., Chirmade, T., Tungekar, A. A., Gani, K. & Bhambure, R. Cloning and expression of antibody fragment (Fab) I: Effect of expression construct and induction strategies on light and heavy chain gene expression. Biochem. Eng. J. 176, 108189 (2021).
doi: 10.1016/j.bej.2021.108189
Ojima-Kato, T. et al. ‘Zipbody’ leucine zipper-fused Fab in E. coli in vitro and in vivo expression systems. Protein Eng. Des. Sel. 29, 149–157 (2016).
pubmed: 26902097 doi: 10.1093/protein/gzw001
Tungekar, A. A. & Ruddock, L. W. Efficient production of Fc fusion proteins in the cytoplasm of Escherichia coli: Dissecting and mitigating redox heterogeneity. Int. J. Mol. Sci. 23, 14740 (2022).
pubmed: 36499069 pmcid: 9737693 doi: 10.3390/ijms232314740
Thies, M. J. W. et al. Folding and oxidation of the antibody domain CH3. J. Mol. Biol. 319, 1267–1277 (2002).
pubmed: 12079363 doi: 10.1016/S0022-2836(02)00375-3
Gunasekaran, K. et al. Enhancing antibody Fc heterodimer formation through electrostatic steering effects: Applications to bispecific molecules and monovalent IgG. J. Biol. Chem. 285, 19637–19646 (2010).
pubmed: 20400508 pmcid: 2885242 doi: 10.1074/jbc.M110.117382
Ridgway, J. B. B., Presta, L. G. & Carter, P. ‘Knobs-into-holes’ engineering of antibody C(H)3 domains for heavy chain heterodimerization. Protein Eng. 9, 617–621 (1996).
pubmed: 8844834 doi: 10.1093/protein/9.7.617
Moore, G. L. et al. A novel bispecific antibody format enables simultaneous bivalent and monovalent co-engagement of distinct target antigens. MAbs 3, 546–557 (2011).
pubmed: 22123055 pmcid: 3242841 doi: 10.4161/mabs.3.6.18123
Davis, J. H. et al. SEEDbodies: Fusion proteins based on strand-exchange engineered domain (SEED) CH3 heterodimers in an Fc analogue platform for asymmetric binders or immunofusions and bispecific antibodies. Protein Eng. Des. Sel. 23, 195–202 (2010).
pubmed: 20299542 doi: 10.1093/protein/gzp094
Choi, H. J., Kim, Y. J., Lee, S. & Kim, Y. S. A heterodimeric fc-Based bispecific antibody simultaneously targeting vegfr-2 and met exhibits potent antitumor activity. Mol. Cancer Ther. 12, 2748–2759 (2013).
pubmed: 24132142 doi: 10.1158/1535-7163.MCT-13-0628
Wozniak-Knopp, G. et al. An antibody with fab-constant domains exchanged for a pair of CH3 domains. PLoS ONE 13, 1–19 (2018).
doi: 10.1371/journal.pone.0195442
Merchant, A. M. et al. An efficient route to human bispecific IgG. Nat. Biotechnol. 16, 677–681 (1998).
pubmed: 9661204 doi: 10.1038/nbt0798-677
Müller, A. et al. Nonnative disulfide bond formation activates the σ32-dependent heat shock response in Escherichia coli. J. Bacteriol. 195, 2807–2816 (2013).
pubmed: 23585533 pmcid: 3697257 doi: 10.1128/JB.00127-13
Dall’Acqua, W., Simon, A. L., Mulkerrin, M. G. & Carter, P. Contribution of domain interface residues to the stability of antibody C(H)3 domain homodimers. Biochemistry 37, 9266–9273 (1998).
pubmed: 9649307 doi: 10.1021/bi980270i
Matthews, B. W. Studies on protein stability with T4 lysozyme. Adv. Protein Chem. 46, 249–278 (1995).
pubmed: 7771320 doi: 10.1016/S0065-3233(08)60337-X
Gaciarz, A. et al. Systematic screening of soluble expression of antibody fragments in the cytoplasm of E. coli. Microb. Cell Fact. 15, 22 (2016).
pubmed: 26809624 pmcid: 4727284 doi: 10.1186/s12934-016-0419-5
Hatahet, F., Nguyen, V. D., Salo, K. E. H. & Ruddock, L. W. Disruption of reducing pathways is not essential for efficient disulfide bond formation in the cytoplasm of E. coli. Microb. Cell Fact. 9, 67 (2010).
pubmed: 20836848 pmcid: 2946281 doi: 10.1186/1475-2859-9-67
Nguyen, V. D. et al. Pre-expression of a sulfhydryl oxidase significantly increases the yields of eukaryotic disulfide bond containing proteins expressed in the cytoplasm of E. coli. Microb. Cell Fact. 10, 1 (2011).
pubmed: 21211066 pmcid: 3022669 doi: 10.1186/1475-2859-10-1
Bhatwa, A. et al. Challenges associated with the formation of recombinant protein inclusion bodies in escherichia coli and strategies to address them for industrial applications. Front. Bioeng. Biotechnol. 9, 1–18 (2021).
doi: 10.3389/fbioe.2021.630551
Chiu, M. L., Goulet, D. R., Teplyakov, A. & Gilliland, G. L. Antibody structure and function: The basis for engineering therapeutics. Antibodies 8, 55 (2019).
pubmed: 31816964 pmcid: 6963682 doi: 10.3390/antib8040055
Tetin, S. Y., Prendergast, F. G. & Venyaminov, S. Y. Accuracy of protein secondary structure determination from circular dichroism spectra based on immunoglobulin examples. Anal. Biochem. 321, 183–187 (2003).
pubmed: 14511682 doi: 10.1016/S0003-2697(03)00458-5
Tetin, S. Y. & Linthicum, D. S. Circular dichroism spectroscopy of monoclonal antibodies that bind a superpotent guanidinium sweetener ligand. Biochemistry 35, 1258–1264 (1996).
pubmed: 8573581 doi: 10.1021/bi951576h
Tetin, S. Y., Denzin, L. K., Weidner, K. M., Voss, E. W. & Mantulin, W. W. Comparative circular dichroism studies of an anti-fluorescein monoclonal antibody (Mab 4-4-20) and its derivatives1. Biochemistry 31, 12029–12034 (1992).
doi: 10.1021/bi00163a010
Akazawa-Ogawa, Y., Nagai, H. & Hagihara, Y. Heat denaturation of the antibody, a multi-domain protein. Biophys. Rev. 10, 255–258 (2018).
pubmed: 29256117 doi: 10.1007/s12551-017-0361-8
Atwell, S., Ridgway, J. B. B., Wells, J. A. & Carter, P. Stable heterodimers from remodeling the domain interface of a homodimer using a phage display library. J. Mol. Biol. 270, 26–35 (1997).
pubmed: 9231898 doi: 10.1006/jmbi.1997.1116
Toughiri, R. et al. Comparing domain interactions within antibody Fabs with kappa and lambda light chains. MAbs 8, 1276–1285 (2016).
pubmed: 27454112 pmcid: 5058631 doi: 10.1080/19420862.2016.1214785
Lilie, H. Folding of the Fab fragment within the intact antibody. FEBS Lett. 417, 239–242 (1997).
pubmed: 9395304 doi: 10.1016/S0014-5793(97)01293-3
Gunasekaran, K., Wittekind, M., Yan, W. & Pentony, M. Method for making antibody Fc-heterodimeric molecules using electrostatic steering effects. WO/2009/089004 (Amgen Inc., 2009).
Gąciarz, A. & Ruddock, L. W. Complementarity determining regions and frameworks contribute to the disulfide bond independent folding of intrinsically stable scFv. PLoS ONE 12, 1–20 (2017).
doi: 10.1371/journal.pone.0189964
Tungekar, A. A. & Ruddock, L. W. Production of neutralizing antibody fragment variants in the cytoplasm of E. coli for rapid screening: SARS-CoV-2 a case study. Sci. Rep. 13, 4408 (2023).
pubmed: 36927743 pmcid: 10019796 doi: 10.1038/s41598-023-31369-2
Hansen, J. et al. Studies in humanized mice and convalescent humans yield a SARS-CoV-2 antibody cocktail. Science 369, 1010–1014 (2020).
pubmed: 32540901 pmcid: 7299284 doi: 10.1126/science.abd0827
Rathore, A. S. & Batra, J. Antibody production in microbial hosts. BioPharm Int. 29, 18–23 (2016).
Brinkmann, U. & Kontermann, R. E. The making of bispecific antibodies. MAbs 9, 182–212 (2017).
pubmed: 28071970 pmcid: 5297537 doi: 10.1080/19420862.2016.1268307
Ha, J. H., Kim, J. E. & Kim, Y. S. Immunoglobulin Fc heterodimer platform technology: From design to applications in therapeutic antibodies and proteins. Front. Immunol. 7, 1–16 (2016).
doi: 10.3389/fimmu.2016.00394
Kontermann, R. E. Dual targeting strategies with bispecific antibodies © 2012 Landes Bioscience. MAbs 4, 182–197 (2012).
pubmed: 22453100 pmcid: 3361654 doi: 10.4161/mabs.4.2.19000
Rader, C. Overview on concepts and applications of fab antibody fragments. Curr. Protoc. Protein Sci. 55, 1–14 (2009).
doi: 10.1002/0471140864.ps0609s55
Eleniste, P. P., Hofstetter, H. & Hofstetter, O. Expression and characterization of an enantioselective antigen-binding fragment directed against α-amino acids. Protein Expr. Purif. 91, 20–29 (2013).
pubmed: 23827208 doi: 10.1016/j.pep.2013.06.010
Demarest, S. J. et al. Engineering stability into Escherichia coli secreted Fabs leads to increased functional expression. Protein Eng. Des. Sel. 19, 325–336 (2006).
pubmed: 16672248 doi: 10.1093/protein/gzl016
Alt, M., Müller, R. & Kontermann, R. E. Novel tetravalent and bispecific IgG-like antibody molecules combining single-chain diabodies with the immunoglobulin γ1 Fc or CH3 region. FEBS Lett. 454, 90–94 (1999).
pubmed: 10413102 doi: 10.1016/S0014-5793(99)00782-6
Lu, D. et al. Di-diabody: A novel tetravalent bispecific antibody molecule by design. J. Immunol. Methods 279, 219–232 (2003).
pubmed: 12969563 doi: 10.1016/S0022-1759(03)00251-5
Hu, S. Z. et al. Minibody: A novel engineered anti-carcinoembryonic antigen antibody fragment (single-chain Fv-CH3) which exhibits rapid, high-level targeting of xenografts. Cancer Res. 56, 3055–3061 (1996).
pubmed: 8674062
Von Kreudenstein, T. S. et al. Improving biophysical properties of a bispecific antibody scaffold to aid developability: Quality by molecular design. MAbs 5, 646–654 (2013).
doi: 10.4161/mabs.25632
Kang, H. J., Kim, H. J., Jung, M. S., Han, J. K. & Cha, S. H. Optimal expression of a Fab-effector fusion protein in Escherichia coli by removing the cysteine residues responsible for an interchain disulfide bond of a Fab molecule. Immunol. Lett. 184, 34–42 (2017).
pubmed: 28216260 doi: 10.1016/j.imlet.2017.02.008
Hölzer, W., Petersen, F., Strittmatter, W., Matzku, S. & Von Hoegen, I. A fusion protein of IL-8 and a Fab antibody fragment binds to IL-8 receptors and induces neutrophil activation. Cytokine 8, 214–221 (1996).
pubmed: 8833036 doi: 10.1006/cyto.1996.0030
Robinson, M. P. et al. Efficient expression of full-length antibodies in the cytoplasm of engineered bacteria. Nat. Commun. 6, 9072 (2015).
doi: 10.1038/ncomms9072
Jung, S. T. et al. Aglycosylated IgG variants expressed in bacteria that selectively bind FcγRI potentiate tumor cell killing by monocyte-dendritic cells. Proc. Natl. Acad. Sci. U. S. A. 107, 604–609 (2010).
pubmed: 20080725 doi: 10.1073/pnas.0908590107
Li, Z., Kessler, W., Van Den Heuvel, J. & Rinas, U. Simple defined autoinduction medium for high-level recombinant protein production using T7-based Escherichia coli expression systems. Appl. Microbiol. Biotechnol. 91, 1203–1213 (2011).
pubmed: 21698378 doi: 10.1007/s00253-011-3407-z
Gasteiger, E. et al. ExPASy: The proteomics server for in-depth protein knowledge and analysis. Nucleic Acids Res. 31, 3784–3788 (2003).
pubmed: 12824418 pmcid: 168970 doi: 10.1093/nar/gkg563

Auteurs

Aatir A Tungekar (AA)

Protein and Structural Biology Research Unit, Faculty of Biochemistry and Molecular Medicine, University of Oulu, 90220, Oulu, Finland.

Lloyd W Ruddock (LW)

Protein and Structural Biology Research Unit, Faculty of Biochemistry and Molecular Medicine, University of Oulu, 90220, Oulu, Finland. lloyd.ruddock@oulu.fi.

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