Experimental phasing opportunities for macromolecular crystallography at very long wavelengths.


Journal

Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670

Informations de publication

Date de publication:
12 Oct 2023
Historique:
received: 27 04 2023
accepted: 26 09 2023
medline: 13 10 2023
pubmed: 13 10 2023
entrez: 12 10 2023
Statut: epublish

Résumé

Despite recent advances in cryo-electron microscopy and artificial intelligence-based model predictions, a significant fraction of structure determinations by macromolecular crystallography still requires experimental phasing, usually by means of single-wavelength anomalous diffraction (SAD) techniques. Most synchrotron beamlines provide highly brilliant beams of X-rays of between 0.7 and 2 Å wavelength. Use of longer wavelengths to access the absorption edges of biologically important lighter atoms such as calcium, potassium, chlorine, sulfur and phosphorus for native-SAD phasing is attractive but technically highly challenging. The long-wavelength beamline I23 at Diamond Light Source overcomes these limitations and extends the accessible wavelength range to λ = 5.9 Å. Here we report 22 macromolecular structures solved in this extended wavelength range, using anomalous scattering from a range of elements which demonstrate the routine feasibility of lighter atom phasing. We suggest that, in light of its advantages, long-wavelength crystallography is a compelling option for experimental phasing.

Identifiants

pubmed: 37828292
doi: 10.1038/s42004-023-01014-0
pii: 10.1038/s42004-023-01014-0
pmc: PMC10570326
doi:

Types de publication

Journal Article

Langues

eng

Pagination

219

Subventions

Organisme : Medical Research Council
ID : MR/S007555/1
Pays : United Kingdom
Organisme : Medical Research Council
ID : MR/K018779/1
Pays : United Kingdom
Organisme : Medical Research Council
ID : MR/V001329/1
Pays : United Kingdom
Organisme : Medical Research Council
ID : MR/L009528/1
Pays : United Kingdom
Organisme : Wellcome Trust
Pays : United Kingdom

Informations de copyright

© 2023. Springer Nature Limited.

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Auteurs

Kamel El Omari (K)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.

Ramona Duman (R)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.

Vitaliy Mykhaylyk (V)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.

Christian M Orr (CM)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.

Merlyn Latimer-Smith (M)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.

Graeme Winter (G)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.

Vinay Grama (V)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.

Feng Qu (F)

Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.
Department of Life Sciences, Imperial College London, London, SW7 2AZ, UK.
Department of Biochemistry, University of Oxford, Oxford, UK.

Kiran Bountra (K)

Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.
Department of Life Sciences, Imperial College London, London, SW7 2AZ, UK.

Hok Sau Kwong (HS)

Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.
Department of Life Sciences, Imperial College London, London, SW7 2AZ, UK.

Maria Romano (M)

Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.
Department of Life Sciences, Imperial College London, London, SW7 2AZ, UK.
Institute of Biostructures and Bioimaging, IBB, CNR, 80131, Naples, Italy.
Department of Pharmacy, University of Naples "Federico II", 80131, Naples, Italy.

Rosana I Reis (RI)

National Physical Laboratory, Hampton Road, Teddington, TW11 0LW, UK.

Lutz Vogeley (L)

Charles River Discovery Research Services UK, Chesterford Research Park, Saffron Walden, CB10 1XL, UK.
Max Planck Institute of Molecular Cell Biology and Genetics (MPI-CBG), Dresden, Germany.

Luca Vecchia (L)

Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.
Friedrich Miescher Institute for Biomedical Research, Basel, Switzerland.

C David Owen (CD)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.

Sina Wittmann (S)

Department of Biochemistry, University of Oxford, Oxford, UK.
Institute of Molecular Biology (IMB), Ackermannweg 4, 55128, Mainz, Germany.

Max Renner (M)

Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.
Department of Chemistry, Umeå University, 901 87, Umeå, Sweden.

Miki Senda (M)

Structural Biology Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki, 305-0801, Japan.

Naohiro Matsugaki (N)

Structural Biology Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki, 305-0801, Japan.
Department of Materials Structure Science, School of High Energy Accelerator Science, The Graduate University of Advanced Studies (Soken-dai), 1-1 Oho, Tsukuba, Ibaraki, 305-0801, Japan.

Yoshiaki Kawano (Y)

Advanced Photon Technology Division, RIKEN SPring-8 Center, Hyogo, 679-5148, Japan.

Thomas A Bowden (TA)

Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.

Isabel Moraes (I)

National Physical Laboratory, Hampton Road, Teddington, TW11 0LW, UK.

Jonathan M Grimes (JM)

Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.

Erika J Mancini (EJ)

School of Life Sciences, University of Sussex, Falmer, Brighton, BN1 9QG, UK.

Martin A Walsh (MA)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.

Cristiane R Guzzo (CR)

Department of Microbiology, Institute of Biomedical Sciences, University of São Paulo, São Paulo, 05508-000, Brazil.

Raymond J Owens (RJ)

Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.
The Rosalind Franklin Institute, Harwell Campus, Oxford, OX11 0FA, UK.

E Yvonne Jones (EY)

Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.

David G Brown (DG)

Charles River Discovery Research Services UK, Chesterford Research Park, Saffron Walden, CB10 1XL, UK.

Dave I Stuart (DI)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK.
Division of Structural Biology, Wellcome Centre for Human Genetics, University of Oxford, Oxford, OX3 7BN, UK.

Konstantinos Beis (K)

Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK.
Department of Life Sciences, Imperial College London, London, SW7 2AZ, UK.

Armin Wagner (A)

Diamond Light Source, Harwell Science and Innovation Campus, -, OX110DE, UK. armin.wagner@diamond.ac.uk.
Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, OX11 0FA, UK. armin.wagner@diamond.ac.uk.

Classifications MeSH