Promotion of phosphate release from humic acid-iron hydroxide coprecipitates in the presence of citric acid.

Phosphate (P) resources are expected to be depleted within a century. Therefore, promoting balanced phosphorus fertilizer use and understanding phosphorus dynamics in soils containing iron (III), organic acids, and iron (III)-organic molecule particulates is crucial. This study investigated the sorption of citric acid onto humic acid-iron hydr(o)xide coprecipitate (HAFHCP) and the reciprocal effects of citric acid and P sorption on HAFHCP with different C/Fe ratios. The results showed that the maximum sorption capacity (MSC) of citric acid on HAFHCP decreased with increasing C/Fe ratios in the HAFHCP. The P sorption on HAFHCP pre-sorbed with citric acids (denoted as C-P) decreased by 50% compared with that of the MSC on FH. However, citric acids could only reduce P sorption by 20% when P was pre-sorbed on HAFHCP (denoted as P-C). The results suggested that upon the formation of HAFHCP, citric acids might increase P availability, especially in the C-P system. Although citric acids initially inhibited P sorption on HAFHCP in the P-C system, P sorption increased with prolonged reaction time. The exposures of new sorption sites upon dissolution of Fe from HAFHCP by citric acids or/and the formations of Fe bridge between P and organic domains of HAFHCP might contribute to these results. Additionally, a number of large HAFHCP aggregates became smaller while sorbing P due to the increasing electric repulsion on the surfaces of FH, enabling the subsequent dissolutions of more Fe by citric acids from HAFHCP in the P-C system. By integrating these innovative and sustainable strategies, the recycling and reuse of P can be optimized, thereby minimizing the reliance on synthetic fertilizers and mitigating environmental impacts. This approach fosters the efficient utilization of phosphorus resources, improves soil fertility, and enhances the overall resilience of agricultural systems and ecosystems.

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Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.