Analysis of natural okra extracts as corrosion inhibitors for mild steel in acidic medium.
Box-Behnken
Corrosion inhibitors
Mild steel
Okra mucilage
Weight loss method
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
Dec 2023
Dec 2023
Historique:
received:
06
02
2023
accepted:
19
10
2023
medline:
7
12
2023
pubmed:
4
11
2023
entrez:
4
11
2023
Statut:
ppublish
Résumé
Plant extracts have been shown to effectively inhibit metal corrosion. Using the Box-Behnken design, gravimetric, and electrochemical techniques, analyses were designed to investigate the anti-corrosion potential of okra in a 1M HCl medium. The inhibition performances derived from the various methods were in good agreement, demonstrating that physio-chemisorption was effective and adhered to the Langmuir isotherm model. The efficiency of okra mucilage extract was 96% at a much lower concentration compared to 91.2% and 88.4% for the unsieved extract and gelly-okra filtrate, respectively. FTIR results showed the presence of several functional groups in the okra mucilage extract that are associated with adsorption, and TGA analysis revealed that the extract has high thermal stability. FESEM analysis also supported evidence of adsorption. It was determined that corrosion inhibition by okra mucilage extract was primarily influenced by temperature, followed by extract concentration, with immersion time having the least effect. From the model optimization, it was observed that okra mucilage extract at 200 ppm, 60°C, and 24 h gave an inhibition efficiency of 89.98% and high desirability. These results demonstrate the high capacity of natural okra as an efficient biodegradable corrosion inhibitor.
Identifiants
pubmed: 37924403
doi: 10.1007/s11356-023-30635-0
pii: 10.1007/s11356-023-30635-0
doi:
Substances chimiques
Steel
12597-69-2
Acids
0
Plant Extracts
0
Polysaccharides
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
119309-119328Informations de copyright
© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
Références
Ahiakpa J, Amoatey H, Amenorpe G, Apatey J, Ayeh E, Agbemavor W (2014) Mucilage content of 21 accessions of okra (Abelmoschus spp L.). Sci Agric 2(2):96–101
Ahmed RK, Zhang S (2021) Atriplex leucoclada extract: a promising eco-friendly anticorrosive agent for copper in aqueous media. J Ind Eng Chem 99:334–343
doi: 10.1016/j.jiec.2021.04.042
Al-Baghdadi S, Gaaz T, Al-Adili A, Al-Amiery A, Takriff M (2021) Experimental studies on corrosion inhibition performance of acetylthiophene thiosemicarbazone for mild steel in HCl complemented with DFT investigation. Int J Low Carbon Technol 16(1):181–188
doi: 10.1093/ijlct/ctaa050
Alamri MS, Mohamed A, Hussain S, Xu J (2012) Effect of okra extract on properties of wheat, corn and rice starches. J Food Agric Environ 10(1):217–222
Ali AE, Badr GE, Fouda A (2021) Citrus sinensis extract as a green inhibitor for the corrosion of carbon steel in sulphuric acid solution. Biointerface Res Appl Chem 11:14007–14020
doi: 10.33263/BRIAC116.1400714020
Amdoun R, Khelifi L, Khelifi-Slaoui M, Amroune S, Asch M, Assaf-Ducrocq C, Gontier E (2018) The desirability optimization methodology; a tool to predict two antagonist responses in biotechnological systems: case of biomass growth and hyoscyamine content in elicited Datura starmonium hairy roots. Iran J Biotechnol 16(1):11–19
doi: 10.21859/ijb.1339
Ameer MA, Fekry AM (2015) Corrosion inhibition by naturally occurring Hibiscus sabdariffa plant extract on a mild steel alloy in HCl solution. Turk J Chem 39(5):1078–1088
doi: 10.3906/kim-1408-69
Anadebe V, Nnaji P, Onukwuli O, Okafor N, Abeng F, Chukwuike V, Okoye C, Udoh I, Chidiebere M, Guo L (2022a) Multidimensional insight into the corrosion inhibition of salbutamol drug molecule on mild steel in oilfield acidizing fluid: experimental and computer aided modeling approach. J Mol Liq 349:118482
doi: 10.1016/j.molliq.2022.118482
Anadebe V, Onukwuli O, Omotioma M, Okafor N (2019) Experimental, theoretical modeling and optimization of inhibition efficiency of pigeon pea leaf extract as anti-corrosion agent of mild steel in acid environment. Mater Chem Phys 233:120–132
doi: 10.1016/j.matchemphys.2019.05.033
Anadebe VC, Chukwuike VI, Ramanathan S, Barik RC (2022b) Cerium-based metal organic framework (Ce-MOF) as corrosion inhibitor for API 5L X65 steel in CO2-saturated brine solution: XPS, DFT/MD-simulation, and machine learning model prediction. Process Saf Environ Prot 168:499–512
doi: 10.1016/j.psep.2022.10.016
Arthur DE, Abechi SE (2019) Corrosion inhibition studies of mild steel using Acalypha chamaedrifolia leaves extract in hydrochloric acid medium. SN Appl Sci 1(9):1–11
doi: 10.1007/s42452-019-1138-4
Azzam EM, Abd El-Salam HM, Mohamed RA, Shaban SM, Shokry A (2018) Control the corrosion of mild steel using synthesized polymers based on polyacrylamide. Egypt J Pet 27(4):897–910
doi: 10.1016/j.ejpe.2018.01.006
Bahlakeh G, Dehghani A, Ramezanzadeh B, Ramezanzadeh M (2019) Highly effective mild steel corrosion inhibition in 1 M HCl solution by novel green aqueous mustard seed extract: experimental, electronic-scale DFT and atomic-scale MC/MD explorations. J Mol Liq 293:111559
doi: 10.1016/j.molliq.2019.111559
Balasubramani P, Palaniswamy P, Visvanathan R, Thirupathi V, Subbarayan A, Maran JP (2015) Microencapsulation of garlic oleoresin using maltodextrin as wall material by spray drying technology. Int J Biol Macromol 72:210–217
doi: 10.1016/j.ijbiomac.2014.08.011
Banerjee S, Srivastava V, Singh M (2012) Chemically modified natural polysaccharide as green corrosion inhibitor for mild steel in acidic medium. Corros Sci 59:35–41
doi: 10.1016/j.corsci.2012.02.009
Bentiss F, Traisnel M, Chaibi N, Mernari B, Vezin H, Lagrenée M (2002) 2, 5-Bis (n-methoxyphenyl)-1, 3, 4-oxadiazoles used as corrosion inhibitors in acidic media: correlation between inhibition efficiency and chemical structure. Corros Sci 44(10):2271–2289
doi: 10.1016/S0010-938X(02)00037-9
Camciuc M, Deplagne M, Vilarem G, Gaset A (1998) Okra—Abelmoschus esculentus L.(Moench.) a crop with economic potential for set aside acreage in France. Ind Crop Prod 7(2–3):257–264
doi: 10.1016/S0926-6690(97)00056-3
Chaubey N, Qurashi A, Chauhan DS, Quraishi M (2020) Frontiers and advances in green and sustainable inhibitors for corrosion applications: a critical review. J Mol Liq 114385
de Alvarenga Pinto Cotrim M, Mottin AC, Ayres E (2016) Preparation and characterization of okra mucilage (Abelmoschus esculentus) edible films. Macromol Symp 367(1):90–100
doi: 10.1002/masy.201600019
De Rosa IM, Kenny JM, Puglia D, Santulli C, Sarasini F (2010) Morphological, thermal and mechanical characterization of okra (Abelmoschus esculentus) fibres as potential reinforcement in polymer composites. Compos Sci Technol 70(1):116–122
doi: 10.1016/j.compscitech.2009.09.013
Dimopoulou M, Ritzoulis C, Panayiotou C (2015) Surface characterization of okra hydrocolloid extract by inverse gas chromatography (IGC). Colloids Surf A Physicochem Eng Asp 475:37–43
doi: 10.1016/j.colsurfa.2014.09.042
El-Etre A (2003) Inhibition of aluminum corrosion using Opuntia extract. Corros Sci 45(11):2485–2495
doi: 10.1016/S0010-938X(03)00066-0
El-Mahdy AR, El-Sebaiy LA (1984) Preliminary studies on the mucilages extracted from okra fruits, Taro tubers, Jew’s mellow leaves and fenugreek seeds. Food Chem 14(4):237–249
doi: 10.1016/0308-8146(84)90079-7
Farooq U, Malviya R, Sharma PK (2013) Extraction and characterization of okra mucilage as pharmaceutical excipient. Acad J Plant Sci 6(4):168–172
Fayomi O, Akande I, Nsikak U (2019) An overview of corrosion inhibition using green and drug inhibitors. J Phys Conf Ser 1378(2):022022
doi: 10.1088/1742-6596/1378/2/022022
Freitas T, Oliveira V, De Souza M, Geraldino H, Almeida V, Fávaro S, Garcia J (2015) Optimization of coagulation-flocculation process for treatment of industrial textile wastewater using okra (a. esculentus) mucilage as natural coagulant. Ind Crop Prod 76:538–544
doi: 10.1016/j.indcrop.2015.06.027
Gaaz TS, Dakhil RM, Jamil DM, Al-Amiery AA, Kadhum AA, Takriff M (2020) Evaluation of green corrosion inhibition by extracts of citrus aurantium leaves against carbon steel in 1 M HCl medium complemented with quantum chemical assessment. Int J Thin Film Sci Technol 9(3):171–179
doi: 10.18576/ijtfst/090307
Gemede HF, Haki GD, Beyene F, Rakshit SK, Woldegiorgis AZ (2018) Indigenous Ethiopian okra (Abelmoschus esculentus) mucilage: a novel ingredient with functional and antioxidant properties. Food Sci Nutr 6(3):563–571
doi: 10.1002/fsn3.596
Guo L, Tan B, Li W, Li Q, Zheng X, Obot IB (2021) Banana leaves water extracts as inhibitor for X70 steel corrosion in HCl medium. J Mol Liq 327:114828
doi: 10.1016/j.molliq.2020.114828
Hassan KH, Khadom AA, Kurshed NH (2016) Citrus aurantium leaves extracts as a sustainable corrosion inhibitor of mild steel in sulfuric acid. S Afr J Chem Eng 22:1–5
Heidarshenas B, Zhou L, Hussain G, Li Q, Ostrikov KK (2020) Green inhibitors for steel corrosion in acidic environment: state-of-art. Mater Today Sustain 10:100044
doi: 10.1016/j.mtsust.2020.100044
Idris MN, Daud AR, Othman NK (2013) Electrochemical impedance spectroscopy study on corrosion inhibition of benzyltriethylammonium chloride. AIP Conf Proc 1571(1):23–28
doi: 10.1063/1.4858624
Instruments G (2007) Basics of electrochemical impedance spectroscopy. In: G. instruments, complex impedance in corrosion, pp 1–30
Khaleel H, Ateeq AA, Ali AA (2018) The effect of temperature and inhibitor on corrosion of carbon steel in acid solution under static study. Int J Appl Eng Res 13(6):3638–3647
Lagrenee M, Mernari B, Chaibi N, Traisnel M, Vezin H, Bentiss F (2001) Investigation of the inhibitive effect of substituted oxadiazoles on the corrosion of mild steel in HCl medium. Corros Sci 43(5):951–962
doi: 10.1016/S0010-938X(00)00076-7
Loto RT, Mbah EH, Ugada JI (2021) Corrosion inhibition effect of citrus sinensis essential oil extract on plain carbon steel in dilute acid media. S Afr J Chem Eng 35:159–164
Maran JP, Manikandan S, Priya B, Gurumoorthi P (2015) Box-Behnken design based multi-response analysis and optimization of supercritical carbon dioxide extraction of bioactive flavonoid compounds from tea (Camellia sinensis L.) leaves. J Food Sci Technol 52(1):92–104
doi: 10.1007/s13197-013-0985-z
Mehmood T, Ahmed A, Ahmad A, Ahmad MS, Sandhu MA (2018) Optimization of mixed surfactants-based β-carotene nanoemulsions using response surface methodology: an ultrasonic homogenization approach. Food Chem 253:179–184
doi: 10.1016/j.foodchem.2018.01.136
Meister JJ, Anderle K, Merriman G (1983) Rheology of aqueous solutions of okra mucilage F. J Rheol 27(1):37–46
doi: 10.1122/1.549721
Miralrio A, Espinoza Vázquez A (2020) Plant extracts as green corrosion inhibitors for different metal surfaces and corrosive media: a review. Processes 8(8):942
doi: 10.3390/pr8080942
Mobin M, Rizvi M (2017) Polysaccharide from Plantago as a green corrosion inhibitor for carbon steel in 1 M HCl solution. Carbohydr Polym 160:172–183
doi: 10.1016/j.carbpol.2016.12.056
Mobtaker H, Azadi M, Hassani N, Neek-Amal M, Rassouli M, Bidi MA (2021) The inhibition performance of quinoa seed on corrosion behavior of carbon steel in the HCl solution; theoretical and experimental evaluations. J Mol Liq 335:116183
doi: 10.1016/j.molliq.2021.116183
Murtaza M, Tariq Z, Zhou X, Al-Shehri D, Mahmoud M, Kamal MS (2021) Okra as an environment-friendly fluid loss control additive for drilling fluids: experimental & modeling studies. J Pet Sci Eng 204:108743
doi: 10.1016/j.petrol.2021.108743
Murungi PI, Sulaimon AA (2022) Ideal corrosion inhibitors: a review of plant extracts as corrosion inhibitors for metal surfaces. Corros Rev 40(2):127–136
doi: 10.1515/corrrev-2021-0051
Murungi PI, Sulaimon AA, Ssembatya O, Nwankwo P (2022) A review of natural polysaccharides as corrosion inhibitors: recent progress and future opportunities. In: SPE Nigeria annual international conference and exhibition. SPE, p D021S007R003
Nahlé A, Abu-Abdoun II, Abdel-Rahman I (2012) Effect of temperature on the corrosion inhibition of trans-4-hydroxy-4′-stilbazole on mild steel in HCl solution. Int J Corros 2012:380329. https://doi.org/10.1155/2012/380329
doi: 10.1155/2012/380329
Odewunmi NA, Solomon MM, Umoren SA, Ali SA (2020) Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions. ACS Omega 5(42):27057–27071
doi: 10.1021/acsomega.0c02345
Oulabbas A, Abderrahmane S, Salcı A, Geçibesler İH, Solmaz R (2022) Adsorption and corrosion inhibition of cactus cladode extract and effect of KI addition on mild steel in 0.5 M H
Pal S, Ji G, Lgaz H, Chung I-M, Prakash R (2020) Lemon seeds as green coating material for mitigation of mild steel corrosion in acid media: molecular dynamics simulations, quantum chemical calculations and electrochemical studies. J Mol Liq 316:113797
doi: 10.1016/j.molliq.2020.113797
Huong DQ, Duong T, Nam PC (2019) Effect of the structure and temperature on corrosion inhibition of thiourea derivatives in 1.0 M HCl solution. ACS omega 4(11):14478–14489
doi: 10.1021/acsomega.9b01599
Raja PB, Sethuraman MG (2008) Natural products as corrosion inhibitor for metals in corrosive media—a review. Mater Lett 62(1):113–116
doi: 10.1016/j.matlet.2007.04.079
Rani B, Basu BBJ (2012) Green inhibitors for corrosion protection of metals and alloys: an overview. Int J Corros
Roy P, Karfa P, Adhikari U, Sukul D (2014a) Corrosion inhibition of mild steel in acidic medium by polyacrylamide grafted guar gum with various grafting percentage: effect of intramolecular synergism. Corros Sci 88:246–253
doi: 10.1016/j.corsci.2014.07.039
Roy P, Pal A, Sukul D (2014b) Origin of the synergistic effect between polysaccharide and thiourea towards adsorption and corrosion inhibition for mild steel in sulphuric acid. RSC Adv 4(21):10607–10613
doi: 10.1039/c3ra46549g
Saxena A, Prasad D, Haldhar R, Singh G, Kumar A (2018) Use of Saraca ashoka extract as green corrosion inhibitor for mild steel in 0.5 M H2SO4. J Mol Liq 258:89–97
doi: 10.1016/j.molliq.2018.02.104
Singh WP, Bockris J (1996) Toxicity issues of organic corrosion inhibitors: applications of QSAR model. Corrosion Nace 96:NACE-96225
Srivastava V, Banerjee S, Singh M (2010) Inhibitive effect of polyacrylamide grafted with fenugreek mucilage on corrosion of mild steel in 0.5 M H2SO4 at 35° C. J Appl Polym Sci 116(2):810–816
doi: 10.1002/app.31559
Srivastava V, Singh M (2010) Corrosion inhibition of mild steel in acidic medium by poly (aniline-co-o-toluidine) doped with p-toluene sulphonic acid. J Appl Electrochem 40(12):2135–2143
doi: 10.1007/s10800-010-0195-6
Sulaimon AA, Murungi PI, Tackie-Otoo BN, Bustam MA, Nwankwo PC (2023) Quantitative and qualitative analyses of grafted okra for corrosion inhibition of mild steel in acidic medium. Front Chem 11:108
doi: 10.3389/fchem.2023.1129673
Tan B, Fu A, Guo L, Ran Y, Xiong J, Marzouki R, Li W (2023) Insight into anti-corrosion mechanism of Dalbergia odorifera leaves extract as a biodegradable inhibitor for X70 steel in sulfuric acid medium. Ind Crop Prod 194:116106
doi: 10.1016/j.indcrop.2022.116106
Tosif MM, Najda A, Bains A, Kaushik R, Dhull SB, Chawla P, Walasek-Janusz M (2021) A comprehensive review on plant-derived mucilage: characterization, functional properties, applications, and its utilization for nanocarrier fabrication. Polymers 13(7):1066
doi: 10.3390/polym13071066
Umoren S, Ogbobe O, Igwe I, Ebenso E (2008) Inhibition of mild steel corrosion in acidic medium using synthetic and naturally occurring polymers and synergistic halide additives. Corros Sci 50(7):1998–2006
doi: 10.1016/j.corsci.2008.04.015
Vaidya NR, Aklujkar P, Rao AR (2022) Modification of natural gums for application as corrosion inhibitor: a review. J Coat Technol Res 19(1):223–239
doi: 10.1007/s11998-021-00510-z
Xu S, Qiang Y, Fu A, Tan B (2021) Luffa cylindrica roem leaves extract as the environment-friendly inhibitor for copper in sulfuric acid environment. J Mol Liq 343:117619
doi: 10.1016/j.molliq.2021.117619
Zaharuddin ND, Noordin MI, Kadivar A (2014) The use of Hibiscus esculentus (Okra) gum in sustaining the release of propranolol hydrochloride in a solid oral dosage form. Biomed Res Int Biomed Res Int 2014:2014:735891. https://doi.org/10.1155/2014/735891
Zarrok H, Zarrouk A, Salghi R, Oudda H, Hammouti B, Touhami ME, Bouachrine M, Boukhris S (2012) A combined experimental and theoretical study on the corrosion inhibition and adsorption behaviour of quinoxaline derivative during carbon steel corrosion in hydrochloric acid. Port Electrochim Acta 30(6):405–417
doi: 10.4152/pea.201206405
Zhang W, Ma Y, Chen L, Wang L-J, Wu Y-C, Li H-J (2020) Aloe polysaccharide as an eco-friendly corrosion inhibitor for mild steel in simulated acidic oilfield water: experimental and theoretical approaches. J Mol Liq 307:112950
doi: 10.1016/j.molliq.2020.112950