Investigation of aclidinium bromide degradation by stability-indicating HPLC methods, characterization of impurities by NMR, and identification of degradation products by LC-MS.


Journal

Journal of pharmaceutical and biomedical analysis
ISSN: 1873-264X
Titre abrégé: J Pharm Biomed Anal
Pays: England
ID NLM: 8309336

Informations de publication

Date de publication:
20 Jan 2024
Historique:
received: 05 08 2023
revised: 29 10 2023
accepted: 02 11 2023
medline: 6 12 2023
pubmed: 10 11 2023
entrez: 10 11 2023
Statut: ppublish

Résumé

Aclidinium bromide (ACL) is a long-acting muscarinic receptor antagonist used for the long-term treatment of chronic obstructive pulmonary disease (COPD). The aim of this study was to investigate the degradation of aclidinium bromide under stress and stability testing conditions, for which we developed and validated the first stability-indicating, specific, precise, accurate, and robust assay and related substances HPLC methods. Nine of the compounds used as reference standards were synthesized and fully characterized by

Identifiants

pubmed: 37948775
pii: S0731-7085(23)00614-3
doi: 10.1016/j.jpba.2023.115845
pii:
doi:

Substances chimiques

aclidinium bromide UQW7UF9N91
Tropanes 0
Muscarinic Antagonists 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

115845

Informations de copyright

Copyright © 2023 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Yücel Yazar (Y)

Erciyes University, Faculty of Pharmacy, Department of Analytical Chemistry, Kayseri, Türkiye; DEVA Holding A.S., R&D Center, Karaağaç Mh. Fatih Blv. No: 26, Kapaklı, Tekirdağ 59510, Türkiye. Electronic address: yyazar@deva.com.tr.

Fatma Gözde Aydın Özel (FG)

DEVA Holding A.S., R&D Center, Karaağaç Mh. Fatih Blv. No: 26, Kapaklı, Tekirdağ 59510, Türkiye.

Esen Bellur Atici (E)

DEVA Holding A.S., R&D Center, Karaağaç Mh. Fatih Blv. No: 26, Kapaklı, Tekirdağ 59510, Türkiye. Electronic address: ebellur@deva.com.tr.

Erkan Yılmaz (E)

Erciyes University, Faculty of Pharmacy, Department of Analytical Chemistry, Kayseri, Türkiye; Erciyes University, Technology Research & Application Center (TAUM), Kayseri 38039, Türkiye; Erciyes University, Nanotechnology Application and Research Center (ERNAM), Kayseri 38039, Türkiye.

İbrahim Narin (İ)

Erciyes University, Faculty of Pharmacy, Department of Analytical Chemistry, Kayseri, Türkiye.

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Classifications MeSH