Stabilization of Colloidal Germanium Nanoparticles: From the Study to the Prospects of the Application in Thin-Film Technology.
germanium
metastable
nanoparticles
subhalide
thin film
Journal
International journal of molecular sciences
ISSN: 1422-0067
Titre abrégé: Int J Mol Sci
Pays: Switzerland
ID NLM: 101092791
Informations de publication
Date de publication:
03 Nov 2023
03 Nov 2023
Historique:
received:
11
09
2023
revised:
24
10
2023
accepted:
28
10
2023
medline:
15
11
2023
pubmed:
14
11
2023
entrez:
14
11
2023
Statut:
epublish
Résumé
We present the stabilization of halide-terminated Ge nanoparticles prepared via a disproportionation reaction of metastable Ge(I)X solutions with well-defined size distribution. Further tailoring of the stability of the Ge nanoparticles was achieved using variations in the substituent. Ge nanoparticles obtained in this way are readily dispersed in organic solvents, long-term colloidally stable, and are perfect prerequisites for thin-film preparation. This gives these nanomaterials a future in surface-dependent optical applications, as shown for the halide-terminated nanoparticles.
Identifiants
pubmed: 37958931
pii: ijms242115948
doi: 10.3390/ijms242115948
pmc: PMC10649905
pii:
doi:
Substances chimiques
Germanium
00072J7XWS
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Références
Chem Soc Rev. 2019 Mar 4;48(5):1342-1361
pubmed: 30688963
Nanoscale. 2013 Jun 7;5(11):4870-83
pubmed: 23619571
Phys Chem Chem Phys. 2015 Jan 7;17(1):97-111
pubmed: 25406613
Chem Commun (Camb). 2005 Apr 14;(14):1914-6
pubmed: 15795786
Chem Commun (Camb). 2019 Aug 7;55(64):9539-9542
pubmed: 31334515
J Phys Chem Lett. 2013 Oct 17;4(20):3392-6
pubmed: 26705582
Small. 2010 Oct 4;6(19):2080-98
pubmed: 20730824
Inorg Chem. 2020 Aug 3;59(15):10996-11008
pubmed: 32686404
Nanoscale. 2020 Jan 28;12(4):2764-2772
pubmed: 31956879
Adv Mater. 2019 Aug;31(32):e1901556
pubmed: 31148285
Small. 2007 Apr;3(4):691-9
pubmed: 17299826
Small. 2007 Apr;3(4):536-57
pubmed: 17340666
Chem Rev. 2015 Oct 14;115(19):10407-9
pubmed: 26463639
Angew Chem Int Ed Engl. 2010 Feb 15;49(8):1362-95
pubmed: 20108287
Chem Commun (Camb). 2019 May 23;55(43):6102-6105
pubmed: 31070202
Nat Commun. 2013;4:2197
pubmed: 23893292
Chem Rev. 2011 Dec 14;111(12):7710-48
pubmed: 21919528
Chem Rev. 2023 Apr 12;123(7):3790-3851
pubmed: 36735598
J Colloid Interface Sci. 2013 Sep 1;405:322-30
pubmed: 23759321
ACS Nano. 2010 Dec 28;4(12):7459-66
pubmed: 21090762
Chem Soc Rev. 2013 Apr 7;42(7):2861-79
pubmed: 23128962
Chempluschem. 2017 Jan;82(1):60-73
pubmed: 31961504
Chem Rev. 2010 Jan;110(1):389-458
pubmed: 19958036
Inorg Chem. 2018 May 7;57(9):5299-5306
pubmed: 29671319
Chem Commun (Camb). 2023 Sep 12;59(73):10835-10865
pubmed: 37608724
Nanoscale. 2015 Feb 14;7(6):2241-4
pubmed: 25565561
ChemSusChem. 2009;2(1):18-45
pubmed: 19142903