Theoretical and practical guidelines for solvent dilution between the two dimensions in online comprehensive two-dimensional liquid chromatography.

Active modulation HILIC x RPLC Online comprehensive 2D-LC Solvent dilution Solvent mismatch

Journal

Journal of chromatography. A
ISSN: 1873-3778
Titre abrégé: J Chromatogr A
Pays: Netherlands
ID NLM: 9318488

Informations de publication

Date de publication:
08 Feb 2024
Historique:
received: 06 12 2023
revised: 23 01 2024
accepted: 07 02 2024
medline: 17 2 2024
pubmed: 17 2 2024
entrez: 16 2 2024
Statut: aheadofprint

Résumé

Online comprehensive two-dimensional liquid chromatography (online LC x LC) has become increasingly popular. Among the different chromatographic modes that can be combined, hydrophilic interaction chromatography (HILIC) and reversed-phase liquid chromatography (RPLC) are particularly interesting because they offer a high degree of orthogonality. However, this combination remains complex due to the incompatibility of the solvents in the two dimensions. To avoid this problem, it is possible to dilute the first dimension (

Identifiants

pubmed: 38364617
pii: S0021-9673(24)00098-0
doi: 10.1016/j.chroma.2024.464725
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

464725

Informations de copyright

Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Megane K Aebischer (MK)

School of Pharmaceutical Sciences, University of Geneva, CMU - Rue Michel Servet 1, 1211, Geneva 4, Switzerland; Institute of Pharmaceutical Sciences of Western Switzerland, University of Geneva, CMU - Rue Michel Servet 1, 1211, Geneva 4, Switzerland.

Soraya Chapel (S)

Laboratoire SMS-EA3233, Université Rouen Normandie, FR3038 INC3M, Unirouen, Place Emile Blondel, F-76821, Mont-Saint-Aignan, France.

Davy Guillarme (D)

School of Pharmaceutical Sciences, University of Geneva, CMU - Rue Michel Servet 1, 1211, Geneva 4, Switzerland; Institute of Pharmaceutical Sciences of Western Switzerland, University of Geneva, CMU - Rue Michel Servet 1, 1211, Geneva 4, Switzerland. Electronic address: davy.guillarme@unige.ch.

Sabine Heinisch (S)

Université de Lyon, Institut des Sciences Analytiques, UMR 5280 CNRS, 5 rue de la Doua, 69100, Villeurbanne, France.

Classifications MeSH