Exploring the reclamation pathway science of Beachwood powder for pharmaceutical acetaminophen drug effluent management.


Journal

PloS one
ISSN: 1932-6203
Titre abrégé: PLoS One
Pays: United States
ID NLM: 101285081

Informations de publication

Date de publication:
2024
Historique:
received: 11 04 2024
accepted: 27 07 2024
medline: 11 10 2024
pubmed: 11 10 2024
entrez: 11 10 2024
Statut: epublish

Résumé

High effective low-cost substance derived from agriculture-based waste towards a circular economy concept showed a significant green approach for pharmaceuticals uptake in aqueous solution. Beachwood sawdust was used as the source of cellulose based adsorbents. Cellulose is isolated from the waste and in parallel magnetite nanoparticles are prepared by the simple co-precipitation technique and the two substances are mixed in various proportions to be acetaminophen adsorbent. Characteristics of the prepared magnetite (M)/sawdust (SD) composite in various proportions (M:SD (1:1), M:SD (1:2), M:SD (1:3), M:SD (1:5) and M:SD (2:1) were assessed using scanning electron microscope (SEM) transmission electron microscope (TEM) and X-ray diffractometer (XRD) which revealed the presence magnetite and cellulose. Also, for the object of recoverable adsorbent, vibrating sample magnetometer (VSM) of the adsorbent is investigated to evaluate its sustainability. The highest removal rate was associated with M:SD (1:2) compared to the other composites and the pristine magnetite or sawdust materials within 2 hours of isotherm time. The adsorption parameters are optimized and the maximal yield is attained at pH (7.0), adsorbent dose of 2.0 g/L at room temperature. The adsorption matrix is following Langmuir model and fitted to the second-order kinetic model. The process is exothermic in nature and highlighted physisorption tendency. The highest monolayer adsorption uptake was investigated at 7.0 mg/g which corresponds to the M:SD (1:2) adsorbent.

Identifiants

pubmed: 39392806
doi: 10.1371/journal.pone.0309552
pii: PONE-D-24-14655
doi:

Substances chimiques

Acetaminophen 362O9ITL9D
Water Pollutants, Chemical 0
Cellulose 9004-34-6
Powders 0
Magnetite Nanoparticles 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e0309552

Informations de copyright

Copyright: © 2024 Hassan et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

Déclaration de conflit d'intérêts

The authors have declared that no competing interests exist.

Auteurs

Ehssan Ahmed Hassan (EA)

Department of Biology, College of Science and Humanities, Prince Sattam bin Abdul Aziz University, Alkharj, Saudi Arabia.
Department of Zoology, Faculty of Science, Suez Canal University, Ismailia, Egypt.

Maha Tony (M)

Basic Engineering Science Department, Faculty of Engineering, Menoufia University, Shebin El-Kom, Egypt.
Advanced Materials/Solar Energy and Environmental Sustainability (AMSEES) Laboratory, Faculty of Engineering, Menoufia University, Shebin El-Kom, Egypt.

Mohamed M Awad (MM)

Department of Mathematics, College of Science and Humanities in Al-Kharj, Prince Sattam bin Abdulaziz University, Al-Kharj, Saudi Arabia.
Department of Mathematics, Faculty of Science, Suez Canal University, El-Sheik Zayed, Ismailia, Egypt.

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Classifications MeSH