Exploring the reclamation pathway science of Beachwood powder for pharmaceutical acetaminophen drug effluent management.
Journal
PloS one
ISSN: 1932-6203
Titre abrégé: PLoS One
Pays: United States
ID NLM: 101285081
Informations de publication
Date de publication:
2024
2024
Historique:
received:
11
04
2024
accepted:
27
07
2024
medline:
11
10
2024
pubmed:
11
10
2024
entrez:
11
10
2024
Statut:
epublish
Résumé
High effective low-cost substance derived from agriculture-based waste towards a circular economy concept showed a significant green approach for pharmaceuticals uptake in aqueous solution. Beachwood sawdust was used as the source of cellulose based adsorbents. Cellulose is isolated from the waste and in parallel magnetite nanoparticles are prepared by the simple co-precipitation technique and the two substances are mixed in various proportions to be acetaminophen adsorbent. Characteristics of the prepared magnetite (M)/sawdust (SD) composite in various proportions (M:SD (1:1), M:SD (1:2), M:SD (1:3), M:SD (1:5) and M:SD (2:1) were assessed using scanning electron microscope (SEM) transmission electron microscope (TEM) and X-ray diffractometer (XRD) which revealed the presence magnetite and cellulose. Also, for the object of recoverable adsorbent, vibrating sample magnetometer (VSM) of the adsorbent is investigated to evaluate its sustainability. The highest removal rate was associated with M:SD (1:2) compared to the other composites and the pristine magnetite or sawdust materials within 2 hours of isotherm time. The adsorption parameters are optimized and the maximal yield is attained at pH (7.0), adsorbent dose of 2.0 g/L at room temperature. The adsorption matrix is following Langmuir model and fitted to the second-order kinetic model. The process is exothermic in nature and highlighted physisorption tendency. The highest monolayer adsorption uptake was investigated at 7.0 mg/g which corresponds to the M:SD (1:2) adsorbent.
Identifiants
pubmed: 39392806
doi: 10.1371/journal.pone.0309552
pii: PONE-D-24-14655
doi:
Substances chimiques
Acetaminophen
362O9ITL9D
Water Pollutants, Chemical
0
Cellulose
9004-34-6
Powders
0
Magnetite Nanoparticles
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e0309552Informations de copyright
Copyright: © 2024 Hassan et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Déclaration de conflit d'intérêts
The authors have declared that no competing interests exist.