Formation kinetics of disinfection byproducts in algal-laden water during chlorination: A new insight into evaluating disinfection formation risk.
Algal metabolites
Disinfection byproducts formation potential
Microcystis aeruginosa
Journal
Environmental pollution (Barking, Essex : 1987)
ISSN: 1873-6424
Titre abrégé: Environ Pollut
Pays: England
ID NLM: 8804476
Informations de publication
Date de publication:
Feb 2019
Feb 2019
Historique:
received:
22
06
2018
revised:
09
10
2018
accepted:
16
10
2018
pubmed:
11
11
2018
medline:
6
3
2019
entrez:
11
11
2018
Statut:
ppublish
Résumé
It is necessary and important to investigate the formation of disinfection byproducts (DBPs) in water treatment systems for the management of disinfection formation risk. In the present study, the formation potential of trichloromethane (TCM) and haloacetic acids in different algal metabolites were compared, and the formation kinetics of these DBPs were investigated. The results indicated that DBP formation potential, the traditional index widely used to evaluate the disinfection formation risk, can represent neither the total precursors of DBPs nor the possible generated amounts of DBPs in drinking water systems. Kinetic analyses showed that the formation of DBPs could be well described by a classical second-order reaction kinetic model and that the actual concentrations of DBPs during chlorination were predictable with the model. The formation of DBPs in drinking water treatment systems was highly dependent on the total precursors of DBPs in water and the formation rate of DBPs with chlorine; the latter is usually underestimated in previous studies. Because of their high reactivity, TCM in hydrophilic extracellular organic matter and trichloroacetic acid in all algal metabolites should be serious considerations in the management of disinfection formation risk.
Identifiants
pubmed: 30414550
pii: S0269-7491(18)32869-0
doi: 10.1016/j.envpol.2018.10.074
pii:
doi:
Substances chimiques
Disinfectants
0
Water Pollutants, Chemical
0
Chlorine
4R7X1O2820
Trichloroacetic Acid
5V2JDO056X
Chloroform
7V31YC746X
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
63-70Informations de copyright
Copyright © 2018 Elsevier Ltd. All rights reserved.