Macrocycle-Directed Construction of Tetrahedral Anion-π Receptors for Nesting Anions with Complementary Geometry.


Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
17 Oct 2019
Historique:
received: 18 07 2019
revised: 07 08 2019
pubmed: 10 8 2019
medline: 28 11 2019
entrez: 10 8 2019
Statut: ppublish

Résumé

Manipulation of the emerging anion-π interactions in a highly cooperative manner through sophisticated host design represents a very challenging task. In this work, unprecedented tetrahedral anion-π receptors have been successfully constructed for complementary accommodation of tetrahedral and relevant anions. The synthesis was achieved by a macrocycle-directed approach by using large macrocycle precursors bearing four reactive sites, which enabled a kinetic-favored pathway and afforded the otherwise inaccessible tetrahedral cages in considerable yields. Crystal structure suggested that the tetrahedral cages have an enclosed three-dimensional cavity surrounded by four electron-deficient triazine faces in a tetrahedral array. The complementary accommodation of a series of tetrahedral and relevant anions including BF

Identifiants

pubmed: 31398268
doi: 10.1002/chem.201903272
doi:

Substances chimiques

Anions 0
Borates 0
Cross-Linking Reagents 0
Macrocyclic Compounds 0
Perchlorates 0
Sulfates 0
Triazines 0
fluoroboric acid H429WZ9FBQ

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

13275-13279

Subventions

Organisme : National Natural Science Foundation of China
ID : 21772203
Organisme : National Natural Science Foundation of China
ID : 21761132024
Organisme : National Natural Science Foundation of China
ID : 91427301
Organisme : National Natural Science Foundation of China
ID : 21871276
Organisme : National Natural Science Foundation of China
ID : 21521002
Organisme : Chinese Academy of Sciences
ID : QYZDJ-SSW-SLH023
Organisme : U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Jian Luo (J)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100190, P. R. China.

Jun Zhu (J)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100190, P. R. China.

De-Hui Tuo (DH)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100190, P. R. China.

Qinqin Yuan (Q)

Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, MS K8-88, Richland, Washington, 99352, USA.

Lei Wang (L)

Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, MS K8-88, Richland, Washington, 99352, USA.

Xue-Bin Wang (XB)

Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, MS K8-88, Richland, Washington, 99352, USA.

Yu-Fei Ao (YF)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.

Qi-Qiang Wang (QQ)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100190, P. R. China.

De-Xian Wang (DX)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100190, P. R. China.

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