CRISPR/Cas13a-Powered Electrochemical Microfluidic Biosensor for Nucleic Acid Amplification-Free miRNA Diagnostics.


Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Dec 2019
Historique:
received: 16 08 2019
revised: 23 09 2019
pubmed: 31 10 2019
medline: 1 5 2020
entrez: 31 10 2019
Statut: ppublish

Résumé

Noncoding small RNAs, such as microRNAs, are becoming the biomarkers of choice for multiple diseases in clinical diagnostics. A dysregulation of these microRNAs can be associated with many different diseases, such as cancer, dementia, and cardiovascular conditions. The key for effective treatment is an accurate initial diagnosis at an early stage, improving the patient's survival chances. In this work, the first clustered regularly interspaced short palindromic repeats (CRISPR)/Cas13a-powered microfluidic, integrated electrochemical biosensor for the on-site detection of microRNAs is introduced. Through this unique combination, the quantification of the potential tumor markers microRNA miR-19b and miR-20a is realized without any nucleic acid amplification. With a readout time of 9 min and an overall process time of less than 4 h, a limit of detection of 10 pm is achieved, using a measuring volume of less than 0.6 µL. Furthermore, the feasibility of the biosensor platform to detect miR-19b in serum samples of children, suffering from brain cancer, is demonstrated. The validation of the obtained results with a standard quantitative real-time polymerase chain reaction method shows the ability of the electrochemical CRISPR-powered system to be a low-cost, easily scalable, and target amplification-free tool for nucleic acid based diagnostics.

Identifiants

pubmed: 31663165
doi: 10.1002/adma.201905311
doi:

Substances chimiques

CRISPR-Associated Proteins 0
MicroRNAs 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e1905311

Subventions

Organisme : Austrian Science Fund
ID : I3194-B26
Organisme : German Research Foundation
ID : EXC-294 (BIOSS)
Organisme : German Research Foundation
ID : UR 70/12-01
Organisme : Austrian Science Fund FWF
ID : I 3194
Pays : Austria
Organisme : German Research Foundation
ID : WE 4733/4
Organisme : Medical University of Vienna
ID : 1244/2016
Organisme : German Research Foundation
ID : UR 70/10-01

Informations de copyright

© 2019 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Références

C. N. Correia, N. C. Nalpas, K. E. McLoughlin, J. A. Browne, S. V. Gordon, D. E. MacHugh, R. G. Shaughnessy, Front. Immunol. 2017, 8, 1.
J. Hausser, M. Zavolan, Nat. Rev. Genet. 2014, 15, 599.
R. M. Graybill, R. C. Bailey, Anal. Chem. 2016, 88, 431.
L. Vaca, Sensors 2014, 14, 9117.
C. H. Hsieh, W. M. Chen, Y. S. Hsieh, Y. C. Fan, P. E. Yang, S. T. Kang, C. T. Liao, Sci. Rep. 2018, 8, 1.
C. C. Pritchard, H. H. Cheng, M. Tewari, Nat. Rev. Genet. 2012, 13, 358.
R. Tavallaie, J. McCarroll, M. Le Grand, N. Ariotti, W. Schuhmann, E. Bakker, R. D. Tilley, D. B. Hibbert, M. Kavallaris, J. J. Gooding, Nat. Nanotechnol. 2018, 13, 1066.
P. Jolly, M. R. Batistuti, A. Miodek, P. Zhurauski, M. Mulato, M. A. Lindsay, P. Estrela, Sci. Rep. 2016, 6, 36719.
C. Feng, X. Mao, H. Shi, B. Bo, X. Chen, T. Chen, X. Zhu, G. Li, Anal. Chem. 2017, 89, 6631.
P. Androvic, L. Valihrach, J. Elling, R. Sjoback, M. Kubista, Nucleic Acids Res. 2017, 45, e144.
T. Tian, J. Wang, X. Zhou, Org. Biomol. Chem. 2015, 13, 2226.
C. Dincer, R. Bruch, A. Kling, P. S. Dittrich, G. A. Urban, Trends Biotechnol. 2017, 35, 728.
C. Dincer, R. Bruch, E. Costa-Rama, M. T. Fernández-Abedul, A. Merkoçi, A. Manz, G. A. Urban, F. Güder, Adv. Mater. 2019, 31, 1806739.
S. Shmakov, O. O. Abudayyeh, K. S. Makarova, Y. I. Wolf, J. S. Gootenberg, E. Semenova, L. Minakhin, J. Joung, S. Konermann, K. Severinov, F. Zhang, E. V. Koonin, Mol. Cell 2015, 60, 385.
M. Huang, X. Zhou, H. Wang, D. Xing, Anal. Chem. 2018, 90, 2193.
R. Hajian, S. Balderston, T. Tran, T. DeBoer, J. Etienne, M. Sandhu, N. A. Wauford, J.-Y. Chung, J. Nokes, M. Athaiya, J. Paredes, R. Peytavi, B. Goldsmith, N. Murthy, I. M. Conboy, K. Aran, Nat. Biomed. Eng. 2019, 3, 427.
K. Pardee, A. A. Green, M. K. Takahashi, D. Braff, G. Lambert, J. W. Lee, T. Ferrante, D. Ma, N. Donghia, M. Fan, N. M. Daringer, I. Bosch, D. M. Dudley, D. H. O'Connor, L. Gehrke, J. J. Collins, Cell 2016, 165, 1255.
S. Y. Li, Q. X. Cheng, X. Y. Li, Z. L. Zhang, S. Gao, R. B. Cao, G. P. Zhao, J. Wang, J. M. Wang, Cell Discovery 2018, 4, 18.
S.-Y. Li, Q.-X. Cheng, J.-K. Liu, X.-Q. Nie, G.-P. Zhao, J. Wang, Cell Res. 2018, 28, 491.
B. Zetsche, J. S. Gootenberg, O. O. Abudayyeh, I. M. Slaymaker, K. S. Makarova, P. Essletzbichler, S. E. Volz, J. Joung, J. Van Der Oost, A. Regev, E. V. Koonin, F. Zhang, Cell 2015, 163, 759.
J. S. Chen, E. Ma, L. B. Harrington, M. Da Costa, X. Tian, J. M. Palefsky, J. A. Doudna, Science 2018, 360, 436.
X. Zuo, C. Fan, H.-Y. Chen, Nat. Biomed. Eng. 2017, 1, 0091.
O. O. Abudayyeh, J. S. Gootenberg, S. Konermann, J. Joung, I. M. Slaymaker, D. B. T. Cox, S. Shmakov, K. S. Makarova, E. Semenova, L. Minakhin, K. Severinov, A. Regev, E. S. Lander, E. V. Koonin, F. Zhang, Science 2016, 353, aaf5573.
Y. Li, S. Li, J. Wang, G. Liu, Trends Biotechnol. 2019, 37, 730.
A. East-Seletsky, M. R. O'Connell, S. C. Knight, D. Burstein, J. H. D. Cate, R. Tjian, J. A. Doudna, Nature 2016, 538, 270.
O. O. Abudayyeh, J. S. Gootenberg, M. J. Kellner, F. Zhang, CRISPR J. 2019, 2, 165.
J. S. Gootenberg, O. O. Abudayyeh, J. W. Lee, P. Essletzbichler, A. J. Dy, J. Joung, V. Verdine, N. Donghia, N. M. Daringer, C. A. Freije, C. Myhrvold, R. P. Bhattacharyya, J. Livny, A. Regev, E. V. Koonin, D. T. Hung, P. C. Sabeti, J. J. Collins, F. Zhang, Science 2017, 356, 438.
J. S. Gootenberg, O. O. Abudayyeh, M. J. Kellner, J. Joung, J. J. Collins, F. Zhang, Science 2018, 360, 439.
O. O. Abudayyeh, J. S. Gootenberg, P. Essletzbichler, S. Han, J. Joung, J. J. Belanto, V. Verdine, D. B. T. Cox, M. J. Kellner, A. Regev, E. S. Lander, D. F. Voytas, A. Y. Ting, F. Zhang, Nature 2017, 550, 280.
K. M. Lewis, A. Ke, Mol. Cell 2017, 65, 377.
I. Moser, G. Jobst, T. Gamp, Verfahren Zur Herstellung Eines “Lab on Chip” Aus Photoresistmaterial Für Medizinisch Diagnostische Anwendungen, 2001, DE000010139742A1.
R. Bruch, A. Kling, G. A. Urban, C. Dincer, JoVE 2017, 56105.
C. Dincer, A. Kling, C. Chatelle, L. Armbrecht, J. Kieninger, W. Weber, G. Urban, Analyst 2016, 141, 6073.
X. Wang, B. L. Holgado, V. Ramaswamy, S. MacK, K. Zayne, M. Remke, X. Wu, L. Garzia, C. Daniels, A. M. Kenney, M. D. Taylor, Neuro-Oncology 2018, 20, 313.
T. Uziel, F. V. Karginov, S. Xie, J. S. Parker, Y.-D. Wang, A. Gajjar, L. He, D. Ellison, R. J. Gilbertson, G. Hannon, M. F. Roussel, Proc. Natl. Acad. Sci. USA 2009, 106, 2812.
D. Hühn, A. N. Kousholt, C. S. Sørensen, A. A. Sartori, Oncogene 2015, 34, 3977.
B. L. Murphy, S. Obad, L. Bihannic, O. Ayrault, F. Zindy, S. Kauppinen, M. F. Roussel, Cancer Res. 2013, 73, 7068.
C. Myhrvold, C. A. Freije, J. S. Gootenberg, O. O. Abudayyeh, H. C. Metsky, A. F. Durbin, M. J. Kellner, A. L. Tan, L. M. Paul, L. A. Parham, K. F. Garcia, K. G. Barnes, B. Chak, A. Mondini, M. L. Nogueira, S. Isern, S. F. Michael, I. Lorenzana, N. L. Yozwiak, B. L. MacInnis, I. Bosch, L. Gehrke, F. Zhang, P. C. Sabeti, Science 2018, 360, 444.
R. Bruch, C. Chatelle, A. Kling, B. Rebmann, S. Wirth, S. Schumann, W. Weber, C. Dincer, G. Urban, Sci. Rep. 2017, 7, 3127.
R. Bruch, G. A. Urban, C. Dincer, Nat. Biomed. Eng. 2019, 3, 419.
O. O. Abudayyeh, J. S. Gootenberg, CRISPR J. 2019, 2, 69.
M. Labib, M. V. Berezovski, Biosens. Bioelectron. 2015, 68, 83.
K. Boriachek, M. Umer, M. N. Islam, V. Gopalan, A. K. Lam, N. T. Nguyen, M. J. A. Shiddiky, Analyst 2018, 143, 1662.
M. Labib, N. Khan, S. M. Ghobadloo, J. Cheng, J. P. Pezacki, M. V. Berezovski, J. Am. Chem. Soc. 2013, 135, 3027.
D. Kong, S. Bi, Z. Wang, J. Xia, F. Zhang, Anal. Chem. 2016, 88, 10667.
Q. Li, F. Zeng, N. Lyu, J. Liang, Analyst 2018, 143, 2304.
H. Zhang, Q. Wang, X. Yang, K. Wang, Q. Li, Z. Li, L. Gao, W. Nie, Y. Zheng, Analyst 2017, 142, 389.
T. Hu, L. Zhang, W. Wen, X. Zhang, S. Wang, Biosens. Bioelectron. 2016, 77, 451.
Y. Wu, K. Sheng, Y. Liu, Q. Yu, B. Ye, Anal. Chim. Acta 2016, 948, 1.
M. Lin, Y. Wen, L. Li, H. Pei, G. Liu, H. Song, X. Zuo, C. Fan, Q. Huang, Anal. Chem. 2014, 86, 2285.
S. Campuzano, R. M. Torrente-Rodríguez, E. Lõpez-Hernández, F. Conzuelo, R. Granados, J. M. Sánchez-Puelles, J. M. Pingarrõn, Angew. Chem., Int. Ed. 2014, 53, 6168.
Z. Cai, Y. Song, Y. Wu, Z. Zhu, C. James, X. Chen, Biosens. Bioelectron. 2013, 41, 783.
F. Bettazzi, E. Hamid-Asl, C. L. Esposito, C. Quintavalle, N. Formisano, S. Laschi, S. Catuogno, M. Iaboni, G. Marrazza, M. Mascini, L. Cerchia, V. De Franciscis, G. Condorelli, I. Palchetti, Anal. Bioanal. Chem. 2013, 405, 1025.
H. Mohammadi, G. Yammouri, A. Amine, Curr. Opin. Electrochem. 2019, 16, 96.
S. Partel, M. Mayer, P. Hudek, C. Diner, J. Kieninger, G. A. Urban, K. Motzek, L. Matay, Microelectron. Eng. 2012, 97, 235.
S. Partel, C. Dincer, S. Kasemann, J. Kieninger, J. Edlinger, G. Urban, ACS Nano 2016, 10, 1086.
V. Matylitskaya, S. Kasemann, G. Urban, C. Dincer, S. Partel, J. Electrochem. Soc. 2018, 165, B127.
R. Bruch, G. A. Urban, C. Dincer, Trends Biotechnol. 2019, 37, 791.

Auteurs

Richard Bruch (R)

Department of Microsystems Engineering (IMTEK), Laboratory for Sensors, University of Freiburg, Georges-Koehler Allee 103, 79110, Freiburg, Germany.
Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), University of Freiburg, Georges-Koehler-Allee 105, 79110, Freiburg, Germany.

Julia Baaske (J)

Faculty of Biology and Signalling Research Centres BIOSS and CIBSS, University of Freiburg, Schaenzlestraße 18, 79104, Freiburg, Germany.

Claire Chatelle (C)

Faculty of Biology and Signalling Research Centres BIOSS and CIBSS, University of Freiburg, Schaenzlestraße 18, 79104, Freiburg, Germany.

Mailin Meirich (M)

Department of Microsystems Engineering (IMTEK), Laboratory for Sensors, University of Freiburg, Georges-Koehler Allee 103, 79110, Freiburg, Germany.

Sibylle Madlener (S)

Department of Pediatrics and Adolescent Medicine, Molecular Neuro-Oncology, Medical University of Vienna, Waehringer Guertel 18-20, 1090, Vienna, Austria.

Wilfried Weber (W)

Faculty of Biology and Signalling Research Centres BIOSS and CIBSS, University of Freiburg, Schaenzlestraße 18, 79104, Freiburg, Germany.

Can Dincer (C)

Department of Microsystems Engineering (IMTEK), Laboratory for Sensors, University of Freiburg, Georges-Koehler Allee 103, 79110, Freiburg, Germany.
Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), University of Freiburg, Georges-Koehler-Allee 105, 79110, Freiburg, Germany.
Department of Bioengineering, Royal School of Mines, Imperial College London, SW7 2AZ, London, UK.

Gerald Anton Urban (GA)

Department of Microsystems Engineering (IMTEK), Laboratory for Sensors, University of Freiburg, Georges-Koehler Allee 103, 79110, Freiburg, Germany.
Freiburg Materials Research Center (FMF), University of Freiburg, Stefan-Meier-Straße 21, 79104, Freiburg, Germany.

Articles similaires

High-throughput Bronchus-on-a-Chip system for modeling the human bronchus.

Akina Mori, Marjolein Vermeer, Lenie J van den Broek et al.
1.00
Humans Bronchi Lab-On-A-Chip Devices Epithelial Cells Goblet Cells
Humans RNA, Circular Exosomes Cell Proliferation Epithelial-Mesenchymal Transition

The significance of miR-124 in the diagnosis and prognosis of glioma: A systematic review.

Elham Ghasemi, Mahdieh Mondanizadeh, Amir Almasi-Hashiani et al.
1.00
Humans MicroRNAs Glioma Prognosis Biomarkers, Tumor

Classifications MeSH