A Lipophilic 4-Phenylbutyric Acid Derivative That Prevents Aggregation and Retention of Misfolded Proteins.


Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
06 Feb 2020
Historique:
received: 18 09 2019
revised: 17 11 2019
pubmed: 28 11 2019
medline: 14 2 2020
entrez: 28 11 2019
Statut: ppublish

Résumé

Chemical chaperones prevent protein aggregation. However, the use of chemical chaperones as drugs against diseases due to protein aggregation is limited by the very high active concentrations (mm range) required to mediate their effect. One of the most common chemical chaperones is 4-phenylbutyric acid (4-PBA). Despite its unfavorable pharmacokinetic properties, 4-PBA was approved as a drug to treat ornithine cycle diseases. Here, we report that 2-isopropyl-4-phenylbutanoic acid (5) has been found to be 2-10-fold more effective than 4-PBA in several in vitro models of protein aggregation. Importantly, compound 5 reduced the secretion rate of autism-linked Arg451Cys Neuroligin3 (R451C NLGN3).

Identifiants

pubmed: 31773792
doi: 10.1002/chem.201904292
doi:

Substances chimiques

Cell Adhesion Molecules, Neuronal 0
Membrane Proteins 0
Nerve Tissue Proteins 0
Phenylbutyrates 0
Protein Aggregates 0
Proteins 0
neuroligin 3 0
4-phenylbutyric acid 7WY7YBI87E

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1834-1845

Subventions

Organisme : Israel Ministry of Science and the Italian Ministry of Foreign Affairs
ID : 3-13325
Organisme : NAAMAT, for the Edelson Foundation prize for outstanding women researchers
Organisme : Navon fellowship for PhD students, awarded by the Israel Ministry of Science, Technology and Space.
Organisme : German-Israeli Foundation for Scientific Research and Development
ID : I-1410-201.9/2017
Organisme : the Israel Ministry of Science and the Italian Ministry of Foreign Affairs
ID : 3-13325
Organisme : the Navon fellowship for PhD students, awarded by the Israel Ministry of Science, Technology and Space.

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Salome Azoulay-Ginsburg (S)

Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel.

Laura Trobiani (L)

Department of Biology and Biotechnology "Charles Darwin", and, Pasteur Institute-Cenci Bolognetti Foundation, Sapienza University of Rome, Piazzale Aldo Moro 5, Rome, 00185, Italy.

Andrea Setini (A)

Department of Biology and Biotechnology "Charles Darwin", and, Pasteur Institute-Cenci Bolognetti Foundation, Sapienza University of Rome, Piazzale Aldo Moro 5, Rome, 00185, Italy.

Flores Lietta Favaloro (FL)

Department of Biology and Biotechnology "Charles Darwin", and, Pasteur Institute-Cenci Bolognetti Foundation, Sapienza University of Rome, Piazzale Aldo Moro 5, Rome, 00185, Italy.

Ezio Giorda (E)

Ospedale Pediatrico Bambin Gesù-Rome, Piazza di Sant'Onofrio 4, Rome, 00165, Italy.

Avi Jacob (A)

Faculty of Life Sciences, Bar-Ilan University, Ramat-Gan, 5290002, Israel.

Hagit Hauschner (H)

Faculty of Life Sciences, Bar-Ilan University, Ramat-Gan, 5290002, Israel.

Laura Levy (L)

Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel.

Gianluca Cestra (G)

Department of Biology and Biotechnology "Charles Darwin", and, Pasteur Institute-Cenci Bolognetti Foundation, Sapienza University of Rome, Piazzale Aldo Moro 5, Rome, 00185, Italy.
Institute of Molecular Biology and Pathology-National Research Council, Sapienza University of Rome, Piazzale Aldo Moro 5, Rome, 00185, Italy.

Antonella De Jaco (A)

Department of Biology and Biotechnology "Charles Darwin", and, Pasteur Institute-Cenci Bolognetti Foundation, Sapienza University of Rome, Piazzale Aldo Moro 5, Rome, 00185, Italy.

Arie Gruzman (A)

Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel.

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