Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties.
catalysis
dendrimer
electrochemistry
ferrocene
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
21 Jan 2020
21 Jan 2020
Historique:
received:
20
12
2019
revised:
17
01
2020
accepted:
19
01
2020
entrez:
25
1
2020
pubmed:
25
1
2020
medline:
6
11
2020
Statut:
epublish
Résumé
The discovery of ferrocene is often associated with the rapid growth of organometallic chemistry. Dendrimers are highly branched macromolecules that can be functionalized at will at all levels of their structure. The functionalization of dendrimers with ferrocene derivatives can be carried out easily as terminal functions on the surface, but also at the core, or at one or several layers inside the structure. This review will focus on phosphorhydrazone dendrimers functionalized with ferrocene derivatives, on the surface, at the core, at all layers or within a single layer inside the structure. The first part will describe the synthesis; the second part will concern the electrochemical properties; and the last part will give several examples concerning catalysis, with complexes of ferrocenyl phosphines used as terminal functions of dendrimers.
Identifiants
pubmed: 31973221
pii: molecules25030447
doi: 10.3390/molecules25030447
pmc: PMC7038025
pii:
doi:
Substances chimiques
Dendrimers
0
Ferrous Compounds
0
Hydrazones
0
Metallocenes
0
ferrocene
U96PKG90JQ
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.
Références
Chem Soc Rev. 2008 Jan;37(1):56-67
pubmed: 18197333
Chem Soc Rev. 2016 Oct 7;45(19):5174-86
pubmed: 26936375
Chemistry. 2015 Apr 20;21(17):6590-604
pubmed: 25767084
J Am Chem Soc. 2006 Dec 20;128(50):15990-1
pubmed: 17165724
Dalton Trans. 2016 Feb 7;45(5):1810-22
pubmed: 26525036
Nat Commun. 2015 Jul 14;6:7722
pubmed: 26169490
Proc Natl Acad Sci U S A. 2013 May 28;110(22):8795-800
pubmed: 23671078
Chembiochem. 2005 Dec;6(12):2207-13
pubmed: 16317767
J Org Chem. 1996 May 31;61(11):3799-3805
pubmed: 11667232
Chem Commun (Camb). 2017 Aug 31;53(71):9830-9838
pubmed: 28745767
Angew Chem Int Ed Engl. 2015 Jan 2;54(1):311-4
pubmed: 25414092
Chem Soc Rev. 2015 Jun 21;44(12):3890-9
pubmed: 25297494
Angew Chem Int Ed Engl. 2013 Mar 25;52(13):3626-9
pubmed: 23427061