A Direct Fluorescent Activity Assay for Glycosyltransferases Enables Convenient High-Throughput Screening: Application to O-GlcNAc Transferase.


Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
08 06 2020
Historique:
received: 13 01 2020
revised: 13 02 2020
pubmed: 25 2 2020
medline: 25 3 2021
entrez: 25 2 2020
Statut: ppublish

Résumé

Glycosyltransferases carry out important cellular functions in species ranging from bacteria to humans. Despite their essential roles in biology, simple and robust activity assays that can be easily applied to high-throughput screening for inhibitors of these enzymes have been challenging to develop. Herein, we report a bead-based strategy to measure the group-transfer activity of glycosyltransferases sensitively using simple fluorescence measurements, without the need for coupled enzymes or secondary reactions. We validate the performance and accuracy of the assay using O-GlcNAc transferase (OGT) as a model system through detailed Michaelis-Menten kinetic analysis of various substrates and inhibitors. Optimization of this assay and application to high-throughput screening enabled screening for inhibitors of OGT, leading to a novel inhibitory scaffold. We believe this assay will prove valuable not only for the study of OGT, but also more widely as a general approach for the screening of glycosyltransferases and other group-transfer enzymes.

Identifiants

pubmed: 32092778
doi: 10.1002/anie.202000621
doi:

Substances chimiques

N-Acetylglucosaminyltransferases EC 2.4.1.-
O-GlcNAc transferase EC 2.4.1.-

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

9601-9609

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Matthew G Alteen (MG)

Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

Christina Gros (C)

Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

Richard W Meek (RW)

York Structural Biology Laboratory, Department of Chemistry, University of York, York, YO10 5DD, UK.

David A Cardoso (DA)

Children's Medical Research Institute, The University of Sydney, Sydney, NSW, 2145, Australia.

Jil A Busmann (JA)

Department of Molecular Biology and Biochemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

Gontran Sangouard (G)

Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

Matthew C Deen (MC)

Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

Hong-Yee Tan (HY)

Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

David L Shen (DL)

Department of Molecular Biology and Biochemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

Cecilia C Russell (CC)

Chemistry, School of Environmental and Life Sciences, The University of Newcastle, University Drive, Callaghan, NSW, 2308, Australia.

Gideon J Davies (GJ)

York Structural Biology Laboratory, Department of Chemistry, University of York, York, YO10 5DD, UK.

Phillip J Robinson (PJ)

Children's Medical Research Institute, The University of Sydney, Sydney, NSW, 2145, Australia.

Adam McCluskey (A)

Chemistry, School of Environmental and Life Sciences, The University of Newcastle, University Drive, Callaghan, NSW, 2308, Australia.

David J Vocadlo (DJ)

Department of Chemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.
Department of Molecular Biology and Biochemistry, Simon Fraser University, Burnaby, BC, V5A 1S6, Canada.

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