High Performance Redox Initiating Systems Based on the Interaction of Silane with Metal Complexes: A Unique Platform for the Preparation of Composites.
2K systems
composite materials
free radical polymerization
redox systems
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
31 Mar 2020
31 Mar 2020
Historique:
received:
20
03
2020
revised:
26
03
2020
accepted:
30
03
2020
entrez:
5
4
2020
pubmed:
5
4
2020
medline:
29
12
2020
Statut:
epublish
Résumé
Currently, Redox Initiating Systems (RISs) of Free Radical Polymerization (FRP) are mainly based on the interaction of aromatic amines with peroxides (e.g., dibenzoyl peroxide (BPO)) that can be both toxic and unstable. In the present work, we aim to replace these hazardous substances in new RIS that can be peroxide-free and amine-free. Our redox two components (2K) initiating system is based on diphenylsilane (DPS) as reducing agent combined with different metal complexes (Mn(acac)
Identifiants
pubmed: 32244467
pii: molecules25071602
doi: 10.3390/molecules25071602
pmc: PMC7180824
pii:
doi:
Substances chimiques
Coordination Complexes
0
Silanes
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Références
Inorg Chem. 2004 Apr 19;43(8):2456-8
pubmed: 15074958
Chem Rev. 2014 Jan 8;114(1):557-89
pubmed: 24083614
Nanoscale Res Lett. 2011 Jul 18;6:457
pubmed: 21767359
Chem Rev. 1996 Feb 1;96(1):339-364
pubmed: 11848756
Chem Soc Rev. 2016 Nov 7;45(22):6165-6212
pubmed: 27819094
J Investig Clin Dent. 2012 Feb;3(1):3-16
pubmed: 22298515
Chem Rev. 2016 Sep 14;116(17):10212-75
pubmed: 26745441