Ligand-dependent downregulation of MR1 cell surface expression.


Journal

Proceedings of the National Academy of Sciences of the United States of America
ISSN: 1091-6490
Titre abrégé: Proc Natl Acad Sci U S A
Pays: United States
ID NLM: 7505876

Informations de publication

Date de publication:
12 05 2020
Historique:
pubmed: 29 4 2020
medline: 22 8 2020
entrez: 29 4 2020
Statut: ppublish

Résumé

The antigen-presenting molecule MR1 presents riboflavin-based metabolites to Mucosal-Associated Invariant T (MAIT) cells. While MR1 egress to the cell surface is ligand-dependent, the ability of small-molecule ligands to impact on MR1 cellular trafficking remains unknown. Arising from an in silico screen of the MR1 ligand-binding pocket, we identify one ligand, 3-([2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-yl]formamido)propanoic acid, DB28, as well as an analog, methyl 3-([2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-yl]formamido)propanoate, NV18.1, that down-regulate MR1 from the cell surface and retain MR1 molecules in the endoplasmic reticulum (ER) in an immature form. DB28 and NV18.1 compete with the known MR1 ligands, 5-OP-RU and acetyl-6-FP, for MR1 binding and inhibit MR1-dependent MAIT cell activation. Crystal structures of the MAIT T cell receptor (TCR) complexed with MR1-DB28 and MR1-NV18.1, show that these two ligands reside within the A'-pocket of MR1. Neither ligand forms a Schiff base with MR1 molecules; both are nevertheless sequestered by a network of hydrophobic and polar contacts. Accordingly, we define a class of compounds that inhibits MR1 cellular trafficking.

Identifiants

pubmed: 32341160
pii: 2003136117
doi: 10.1073/pnas.2003136117
pmc: PMC7229755
doi:

Substances chimiques

Histocompatibility Antigens Class I 0
Ligands 0
MR1 protein, human 0
Minor Histocompatibility Antigens 0
Receptors, Antigen, T-Cell, alpha-beta 0
Riboflavin TLM2976OFR

Banques de données

PDB
['6PVC', '6PVD']

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

10465-10475

Subventions

Organisme : Medical Research Council
ID : MR/S005382/1
Pays : United Kingdom
Organisme : Cancer Research UK
ID : C399/A2291
Pays : United Kingdom
Organisme : Cancer Research UK
ID : 11331
Pays : United Kingdom
Organisme : BLRD VA
ID : I01 BX000533
Pays : United States
Organisme : Wellcome Trust
ID : 081569/Z/06/Z
Pays : United Kingdom
Organisme : Wellcome Trust
Pays : United Kingdom
Organisme : Medical Research Council
ID : MR/S000542/1
Pays : United Kingdom
Organisme : NIAID NIH HHS
ID : R01 AI134790
Pays : United States

Informations de copyright

Copyright © 2020 the Author(s). Published by PNAS.

Déclaration de conflit d'intérêts

The authors declare no competing interest.

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Auteurs

Mariolina Salio (M)

MRC Human Immunology Unit, MRC Weatherall Institute of Molecular Medicine, University of Oxford, Oxford OX3 9DS, United Kingdom; mariolina.salio@imm.ox.ac.uk g.besra@bham.ac.uk.

Wael Awad (W)

Infection and Immunity Program, Biomedicine Discovery Institute, Monash University, Clayton, VIC 3800, Australia.
Department of Biochemistry and Molecular Biology, Monash University, Clayton, VIC 3800, Australia.

Natacha Veerapen (N)

Institute of Microbiology and Infection, School of Biosciences, University of Birmingham, Edgbaston B15 2TT, Birmingham, United Kingdom.

Claudia Gonzalez-Lopez (C)

MRC Human Immunology Unit, MRC Weatherall Institute of Molecular Medicine, University of Oxford, Oxford OX3 9DS, United Kingdom.

Corinna Kulicke (C)

Division of Pulmonary and Critical Care Medicine, Department of Medicine, Oregon Health & Science University, Portland, OR 97239.
Research Department, Portland Veterans Administration Healthcare System, Portland, OR 97239.

Dominic Waithe (D)

MRC Centre for Computational Biology, The Wolfson Imaging Centre, MRC Weatherall Institute of Molecular Medicine, University of Oxford, Oxford OX3 9DS, United Kingdom.

Anne W J Martens (AWJ)

MRC Human Immunology Unit, MRC Weatherall Institute of Molecular Medicine, University of Oxford, Oxford OX3 9DS, United Kingdom.

David M Lewinsohn (DM)

Division of Pulmonary and Critical Care Medicine, Department of Medicine, Oregon Health & Science University, Portland, OR 97239.
Research Department, Portland Veterans Administration Healthcare System, Portland, OR 97239.

Judith V Hobrath (JV)

Drug Discovery Unit, College of Life Sciences, University of Dundee, Dundee DD1 5EH, United Kingdom.

Liam R Cox (LR)

School of Chemistry, University of Birmingham, Birmingham B15 2TT, United Kingdom.

Jamie Rossjohn (J)

Infection and Immunity Program, Biomedicine Discovery Institute, Monash University, Clayton, VIC 3800, Australia.
Department of Biochemistry and Molecular Biology, Monash University, Clayton, VIC 3800, Australia.
Australian Research Council Centre of Excellence in Advanced Molecular Imaging, Monash University, Clayton, VIC 3800, Australia.
Institute of Infection and Immunity, Cardiff University School of Medicine, Heath Park, Cardiff CF14 4XN, United Kingdom.

Gurdyal S Besra (GS)

Institute of Microbiology and Infection, School of Biosciences, University of Birmingham, Edgbaston B15 2TT, Birmingham, United Kingdom; mariolina.salio@imm.ox.ac.uk g.besra@bham.ac.uk.

Vincenzo Cerundolo (V)

MRC Human Immunology Unit, MRC Weatherall Institute of Molecular Medicine, University of Oxford, Oxford OX3 9DS, United Kingdom.

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Classifications MeSH