Tuning the Innate Immune Response to Cyclic Dinucleotides by Using Atomic Mutagenesis.


Journal

Chembiochem : a European journal of chemical biology
ISSN: 1439-7633
Titre abrégé: Chembiochem
Pays: Germany
ID NLM: 100937360

Informations de publication

Date de publication:
14 09 2020
Historique:
received: 15 03 2020
revised: 24 04 2020
pubmed: 30 4 2020
medline: 8 7 2021
entrez: 30 4 2020
Statut: ppublish

Résumé

Cyclic dinucleotides (CDNs) trigger the innate immune response in eukaryotic cells through the stimulator of interferon genes (STING) signaling pathway. To decipher this complex cellular process, a better correlation between structure and downstream function is required. Herein, we report the design and immunostimulatory effect of a novel group of c-di-GMP analogues. By employing an "atomic mutagenesis" strategy, changing one atom at a time, a class of gradually modified CDNs was prepared. These c-di-GMP analogues induce type-I interferon (IFN) production, with some being more potent than c-di-GMP, their native archetype. This study demonstrates that CDN analogues bearing modified nucleobases are able to tune the innate immune response in eukaryotic cells.

Identifiants

pubmed: 32346955
doi: 10.1002/cbic.202000162
pmc: PMC7494572
mid: NIHMS1595579
doi:

Substances chimiques

Nucleotides, Cyclic 0
Interferons 9008-11-1
Cyclic GMP H2D2X058MU

Types de publication

Journal Article Research Support, N.I.H., Extramural

Langues

eng

Sous-ensembles de citation

IM

Pagination

2595-2598

Subventions

Organisme : NIGMS NIH HHS
ID : R01 GM069773
Pays : United States
Organisme : NIGMS NIH HHS
ID : R01 GM124589
Pays : United States

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Yao Li (Y)

Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358, USA.

Andrea Fin (A)

Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358, USA.

Alexander R Rovira (AR)

Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358, USA.

Yichi Su (Y)

Department of Chemistry and Department of Molecular and Cell Biology, University of California, Berkeley, CA 94720, USA.

Andrew B Dippel (AB)

Department of Chemistry and Department of Molecular and Cell Biology, University of California, Berkeley, CA 94720, USA.

Jonathan Andrés Valderrama (JA)

Collaborative to Halt Antibiotic-Resistant Microbes, Department of Pediatrics, University of California, San Diego, La Jolla, CA 92093-0760, USA.

Angelica M Riestra (AM)

Collaborative to Halt Antibiotic-Resistant Microbes, Department of Pediatrics, University of California, San Diego, La Jolla, CA 92093-0760, USA.

Victor Nizet (V)

Collaborative to Halt Antibiotic-Resistant Microbes, Department of Pediatrics, University of California, San Diego, La Jolla, CA 92093-0760, USA.
Skaggs School of Pharmacy & Pharmaceutical Sciences, University of California, San Diego, La Jolla, CA 92093-0760, USA.

Ming C Hammond (MC)

Department of Chemistry and Department of Molecular and Cell Biology, University of California, Berkeley, CA 94720, USA.
Department of Chemistry and Henry Eyring Center for Cell and Genome Sciences, University of Utah, Salt Lake City, UT 84112, USA.

Yitzhak Tor (Y)

Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358, USA.

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Classifications MeSH