Design and Synthesis of Dihydroxamic Acids as HDAC6/8/10 Inhibitors.


Journal

ChemMedChem
ISSN: 1860-7187
Titre abrégé: ChemMedChem
Pays: Germany
ID NLM: 101259013

Informations de publication

Date de publication:
03 07 2020
Historique:
received: 06 03 2020
revised: 23 04 2020
pubmed: 30 4 2020
medline: 16 6 2021
entrez: 30 4 2020
Statut: ppublish

Résumé

We report the synthesis and evaluation of a class of selective multitarget agents for the inhibition of HDAC6, HDAC8, and HDAC10. The concept for this study grew out of a structural analysis of the two selective inhibitors Tubastatin A (HDAC6/10) and PCI-34051 (HDAC8), which we recognized share the same N-benzylindole core. Hybridization of the two inhibitor structures resulted in dihydroxamic acids with benzyl-indole and -indazole core motifs. These substances exhibit potent activity against HDAC6, HDAC8, and HDAC10, while retaining selectivity over HDAC1, HDAC2, and HDAC3. The best substance inhibited the viability of the SK-N-BE(2)C neuroblastoma cell line with an IC

Identifiants

pubmed: 32348628
doi: 10.1002/cmdc.202000149
pmc: PMC7335359
mid: NIHMS1590164
doi:

Substances chimiques

Histone Deacetylase Inhibitors 0
Hydroxamic Acids 0
Repressor Proteins 0
HDAC6 protein, human EC 3.5.1.98
HDAC8 protein, human EC 3.5.1.98
Histone Deacetylase 6 EC 3.5.1.98
Histone Deacetylases EC 3.5.1.98

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

1163-1174

Subventions

Organisme : NIGMS NIH HHS
ID : R01 GM049758
Pays : United States

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Michael Morgen (M)

Cancer Drug Development Group, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany.

Raphael R Steimbach (RR)

Cancer Drug Development Group, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany.
Faculty of Biosciences, University of Heidelberg, 69120, Heidelberg, Germany.

Magalie Géraldy (M)

Cancer Drug Development Group, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany.

Lars Hellweg (L)

Cancer Drug Development Group, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany.

Peter Sehr (P)

Chemical Biology Core Facility, European Molecular Biology Laboratory (EMBL), 69117, Heidelberg, Germany.

Johannes Ridinger (J)

Hopp Children's Cancer Center Heidelberg (KiTZ), 69120, Heidelberg, Germany.
Clinical Cooperation Unit Pediatric Oncology, German Cancer Research Center (DKFZ), 69120, Heidelberg, Germany.
Department of Pediatric Oncology, Hematology and Immunology, University Hospital Heidelberg, 69120, Heidelberg, Germany.

Olaf Witt (O)

Hopp Children's Cancer Center Heidelberg (KiTZ), 69120, Heidelberg, Germany.
Clinical Cooperation Unit Pediatric Oncology, German Cancer Research Center (DKFZ), 69120, Heidelberg, Germany.
Department of Pediatric Oncology, Hematology and Immunology, University Hospital Heidelberg, 69120, Heidelberg, Germany.
German Cancer Consortium (DKTK), 69120, Heidelberg, Germany.

Ina Oehme (I)

Hopp Children's Cancer Center Heidelberg (KiTZ), 69120, Heidelberg, Germany.
Clinical Cooperation Unit Pediatric Oncology, German Cancer Research Center (DKFZ), 69120, Heidelberg, Germany.
Department of Pediatric Oncology, Hematology and Immunology, University Hospital Heidelberg, 69120, Heidelberg, Germany.

Corey J Herbst-Gervasoni (CJ)

Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA.

Jeremy D Osko (JD)

Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA.

Nicholas J Porter (NJ)

Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA.

David W Christianson (DW)

Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA.

Nikolas Gunkel (N)

Cancer Drug Development Group, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany.
German Cancer Consortium (DKTK), 69120, Heidelberg, Germany.

Aubry K Miller (AK)

Cancer Drug Development Group, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany.
German Cancer Consortium (DKTK), 69120, Heidelberg, Germany.

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Classifications MeSH