Enhanced Redox Reactivity of a Nonheme Iron(V)-Oxo Complex Binding Proton.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
09 09 2020
09 09 2020
Historique:
pubmed:
14
8
2020
medline:
20
4
2021
entrez:
14
8
2020
Statut:
ppublish
Résumé
Acid effects on the chemical properties of metal-oxygen intermediates have attracted much attention recently, such as the enhanced reactivity of high-valent metal(IV)-oxo species by binding proton(s) or Lewis acidic metal ion(s) in redox reactions. Herein, we report for the first time the proton effects of an iron(V)-oxo complex bearing a negatively charged tetraamido macrocyclic ligand (TAML) in oxygen atom transfer (OAT) and electron-transfer (ET) reactions. First, we synthesized and characterized a mononuclear nonheme Fe(V)-oxo TAML complex (
Identifiants
pubmed: 32786748
doi: 10.1021/jacs.0c05108
doi:
Substances chimiques
Iron Compounds
0
Protons
0
Oxygen
S88TT14065
Types de publication
Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.
Langues
eng
Sous-ensembles de citation
IM
Pagination
15305-15319Subventions
Organisme : NIGMS NIH HHS
ID : P41 GM103393
Pays : United States