Asparaginyl Ligases: New Enzymes for the Protein Engineer's Toolbox.


Journal

Chembiochem : a European journal of chemical biology
ISSN: 1439-7633
Titre abrégé: Chembiochem
Pays: Germany
ID NLM: 100937360

Informations de publication

Date de publication:
15 06 2021
Historique:
revised: 08 03 2021
received: 16 02 2021
pubmed: 10 3 2021
medline: 29 12 2021
entrez: 9 3 2021
Statut: ppublish

Résumé

Enzyme-catalysed site-specific protein modifications enable the precision manufacture of conjugates for the study of protein function and/or for therapeutic or diagnostic applications. Asparaginyl ligases are a class of highly efficient transpeptidases with the capacity to modify proteins bearing only a tripeptide recognition motif. Herein, we review the types of protein modification that are accessible using these enzymes, including N- and C-terminal protein labelling, head-to-tail cyclisation, and protein-protein conjugation. We describe the progress that has been made to engineer highly efficient ligases as well as efforts to chemically manipulate the enzyme reaction to favour product formation. These enzymes are powerful additions to the protein engineer's toolbox.

Identifiants

pubmed: 33687132
doi: 10.1002/cbic.202100071
doi:

Substances chimiques

Cysteine Endopeptidases EC 3.4.22.-
asparaginylendopeptidase EC 3.4.22.34

Types de publication

Journal Article Research Support, Non-U.S. Gov't Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

2079-2086

Subventions

Organisme : Australian Research Council (ARC)
ID : FL150100146
Organisme : Ames Research Center NASA
ID : DP200101299
Pays : United States
Organisme : Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science
ID : CE200100012

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Fabian B H Rehm (FBH)

Institute for Molecular Bioscience, Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science, The University of Queensland, Brisbane, QLD 4072, Australia.

Tristan J Tyler (TJ)

Institute for Molecular Bioscience, Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science, The University of Queensland, Brisbane, QLD 4072, Australia.

Jing Xie (J)

Institute for Molecular Bioscience, Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science, The University of Queensland, Brisbane, QLD 4072, Australia.

Kuok Yap (K)

Institute for Molecular Bioscience, Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science, The University of Queensland, Brisbane, QLD 4072, Australia.

Thomas Durek (T)

Institute for Molecular Bioscience, Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science, The University of Queensland, Brisbane, QLD 4072, Australia.

David J Craik (DJ)

Institute for Molecular Bioscience, Australian Research Council Centre of Excellence for Innovations in Peptide and Protein Science, The University of Queensland, Brisbane, QLD 4072, Australia.

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Classifications MeSH