Regulation of Multicolor Fluorescence Changes Found in Donor-acceptor-type Mechanochromic Fluorescent Dyes.

benzothiadiazoles donor-acceptor mechanochromic fluorescence multicolor fluorescence triphenylamines

Journal

Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643

Informations de publication

Date de publication:
02 Aug 2021
Historique:
revised: 12 06 2021
received: 19 05 2021
pubmed: 20 6 2021
medline: 15 9 2021
entrez: 19 6 2021
Statut: ppublish

Résumé

The regulation of multicolor fluorescence changes in mechanochromic fluorescence (MCF) remains a challenging task. Herein, we report the regulation of MCF using a donor-acceptor structure. Two crystal polymorphs, BTD-pCHO(O) and BTD-pCHO(R) produced by the introduction of formyl groups to an MCF dye, respond to a mechanical stimulus, allowing a three-color fluorescence change. Specifically, the orange-colored fluorescence of the metastable BTD-pCHO(O) polymorph changed to a deep-red color in the amorphous-like state to finally give a red color in the stable BTD-pCHO(R) polymorph. This change occurred by mechanical grinding followed by vapor fuming. The two different crystal packing patterns were selectively regulated by the electronic effect of the introduced functional groups. The two types of selectively formed crystals in BTD(F)-pCHO bearing fluorine atoms, and BTD(OMe)-pCHO bearing methoxy groups, respond to mechanical grinding, allowing for the regulation of multicolor MCL from a three-color change to two different types of two-color changes.

Identifiants

pubmed: 34145774
doi: 10.1002/asia.202100538
doi:

Substances chimiques

Fluorescent Dyes 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2136-2145

Subventions

Organisme : Kyushu University
Organisme : Cooperative Research Program of Network Joint Research Center
Organisme : Institute for Materials Chemistry and Engineering, Kyushu University
ID : 20202018
Organisme : Institute for Materials Chemistry and Engineering, Kyushu University
ID : 20212012

Informations de copyright

© 2021 Wiley-VCH GmbH.

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The small internal space in BTD-pCHO(R) seems to be inconsistent with the finding that the crystal density (1.338 g cm−3) of BTD-pCHO(R) is smaller than that (1.358 g cm−3) of BTD-pCHO(O). However, the crystal density is determined by the three-dimensional packing structure. The internal space is focused on the one-dimensional direction. In BTD-pCHO(O) with large internal space, the closely packed structure was found in the two-dimensional direction among the one-dimensional structures (Figure S16d), leading to the large value of crystal density.
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Auteurs

Tsutomu Ishi-I (T)

Department of Biochemistry and Applied Chemistry, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.

Honoka Tanaka (H)

Department of Biochemistry and Applied Chemistry, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.
Material Engineering Advanced Course, Advanced Engineering School, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.

Rihoko Kichise (R)

Department of Biochemistry and Applied Chemistry, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.
Material Engineering Advanced Course, Advanced Engineering School, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.

Christopher Davin (C)

Department of Biochemistry and Applied Chemistry, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.

Takaaki Matsuda (T)

Department of Biochemistry and Applied Chemistry, National Institute of Technology, Kurume College, 1-1-1 Komorino, Kurume, 830-8555, Japan.

Naoya Aizawa (N)

INAMORI Frontier Research Center (IFRC), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.

In Seob Park (IS)

INAMORI Frontier Research Center (IFRC), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.

Takuma Yasuda (T)

INAMORI Frontier Research Center (IFRC), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.

Taisuke Matsumoto (T)

Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-kohen, Kasuga, 816-8580, Japan.

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