Ag(I) Pyridine-Amidoxime Complex as the Catalysis Activity Domain for the Rapid Hydrolysis of Organothiophosphate-Based Nerve Agents: Mechanistic Evaluation and Application.
Catalysis
Coordination Complexes
/ chemistry
Fenitrothion
/ chemistry
Hydrolysis
Methyl Parathion
/ chemistry
Models, Chemical
Molecularly Imprinted Polymers
/ chemistry
Nerve Agents
/ chemistry
Organothiophosphates
/ chemistry
Oximes
/ chemistry
Parathion
/ chemistry
Pyridines
/ chemistry
Silver
/ chemistry
Ag(I) pyridylamine oxime complex
DFT
molecular imprinting polymer catalyst
nerve agent
organothiophosphate catalytic hydrolysis
Journal
ACS applied materials & interfaces
ISSN: 1944-8252
Titre abrégé: ACS Appl Mater Interfaces
Pays: United States
ID NLM: 101504991
Informations de publication
Date de publication:
28 Jul 2021
28 Jul 2021
Historique:
pubmed:
20
7
2021
medline:
23
11
2021
entrez:
19
7
2021
Statut:
ppublish
Résumé
Two novel Ag(I) complexes containing synergistic pyridine and amidoxime ligands (Ag-DPAAO and Ag-PAAO) were first designed as complex monomers. Taking advantage of the molecular imprinting technique and solvothermal method, molecular imprinted porous cross-linked polymers (MIPCPs) were developed as a robust platform for the first time to incorporate Ag-PAAO into a polymer material as a recyclable catalyst. Advantageously, the observed pseudo first-order rate constant (
Identifiants
pubmed: 34278774
doi: 10.1021/acsami.1c09003
doi:
Substances chimiques
Coordination Complexes
0
Molecularly Imprinted Polymers
0
Nerve Agents
0
Organothiophosphates
0
Oximes
0
Pyridines
0
amidoxime
0
Silver
3M4G523W1G
Methyl Parathion
41BCL2O91D
Parathion
61G466064D
Fenitrothion
W8M4X3Y7ZY
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM