Affinity-based profiling of endogenous phosphoprotein phosphatases by mass spectrometry.


Journal

Nature protocols
ISSN: 1750-2799
Titre abrégé: Nat Protoc
Pays: England
ID NLM: 101284307

Informations de publication

Date de publication:
10 2021
Historique:
received: 08 02 2021
accepted: 12 07 2021
pubmed: 15 9 2021
medline: 18 11 2021
entrez: 14 9 2021
Statut: ppublish

Résumé

Phosphoprotein phosphatases (PPPs) execute >90% of serine/threonine dephosphorylation in cells and tissues. While the role of PPPs in cell biology and diseases such as cancer, cardiac hypertrophy and Alzheimer's disease is well established, the molecular mechanisms governing and governed by PPPs still await discovery. Here we describe a chemical proteomic strategy, phosphatase inhibitor beads and mass spectrometry (PIB-MS), that enables the identification and quantification of PPPs and their posttranslational modifications in as little as 12 h. Using a specific but nonselective PPP inhibitor immobilized on beads, PIB-MS enables the efficient affinity-capture, identification and quantification of endogenous PPPs and associated proteins ('PPPome') from cells and tissues. PIB-MS captures functional, endogenous PPP subunit interactions and enables discovery of new binding partners. It performs PPP enrichment without exogenous expression of tagged proteins or specific antibodies. Because PPPs are among the most conserved proteins across evolution, PIB-MS can be employed in any cell line, tissue or organism.

Identifiants

pubmed: 34518704
doi: 10.1038/s41596-021-00604-3
pii: 10.1038/s41596-021-00604-3
pmc: PMC8822503
mid: NIHMS1774052
doi:

Substances chimiques

Phosphoprotein Phosphatases EC 3.1.3.16

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

4919-4943

Subventions

Organisme : Wellcome Trust
Pays : United Kingdom
Organisme : NCI NIH HHS
ID : R33 CA225458
Pays : United States

Informations de copyright

© 2021. The Author(s), under exclusive licence to Springer Nature Limited.

Références

Brautigan, D. L. & Shenolikar, S. Protein serine/threonine phosphatases: keys to unlocking regulators and substrates. Annu. Rev. Biochem. 87, 921–964 (2018).
pubmed: 29925267 doi: 10.1146/annurev-biochem-062917-012332
Virshup, D. M. & Shenolikar, S. From promiscuity to precision: protein phosphatases get a makeover. Mol. Cell 33, 537–545 (2009).
pubmed: 19285938 doi: 10.1016/j.molcel.2009.02.015
Brautigan, D. L. Protein Ser/Thr phosphatases—the ugly ducklings of cell signalling. FEBS J. 280, 324–345 (2013).
pubmed: 22519956 doi: 10.1111/j.1742-4658.2012.08609.x
Sun, L. et al. Inhibition of protein phosphatase 2A- and protein phosphatase 1-induced tau hyperphosphorylation and impairment of spatial memory retention in rats. Neuroscience 118, 1175–1182 (2003).
pubmed: 12732260 doi: 10.1016/S0306-4522(02)00697-8
Kamat, P. K., Rai, S. & Nath, C. Okadaic acid induced neurotoxicity: an emerging tool to study Alzheimer’s disease pathology. Neurotoxicology 37, 163–172 (2013).
pubmed: 23688530 doi: 10.1016/j.neuro.2013.05.002
Sontag, J. M., Nunbhakdi-Craig, V., White, C. L., Halpain, S. & Sontag, E. The protein phosphatase PP2A/Bα binds to the microtubule-associated proteins Tau and MAP2 at a motif also recognized by the kinase Fyn: Implications for tauopathies. J. Biol. Chem. 287, 14984–14993 (2012).
pubmed: 22403409 pmcid: 3340226 doi: 10.1074/jbc.M111.338681
Chen, W. et al. Identification of specific PP2A complexes involved in human cell transformation. Cancer Cell 5, 127–136 (2004).
pubmed: 14998489 doi: 10.1016/S1535-6108(04)00026-1
Arroyo, J. D. & Hahn, W. C. Involvement of PP2A in viral and cellular transformation. Oncogene 24, 7746–7755 (2005).
pubmed: 16299534 doi: 10.1038/sj.onc.1209038
Molkentin, J. D. et al. A calcineurin-dependent transcriptional pathway for cardiac hypertrophy. Cell 93, 215–228 (1998).
pubmed: 9568714 pmcid: 4459646 doi: 10.1016/S0092-8674(00)81573-1
Lyons, S. P. et al. A quantitative chemical proteomic strategy for profiling phosphoprotein phosphatases from yeast to humans. Mol. Cell Proteomics 17, 2448–2461 (2018).
pubmed: 30228194 pmcid: 6283287 doi: 10.1074/mcp.RA118.000822
Nasa, I. et al. Quantitative kinase and phosphatase profiling reveal that CDK1 phosphorylates PP2Ac to promote mitotic entry. Sci. Signal. 13, eaba7823 (2020).
pubmed: 32900880 pmcid: 7579721 doi: 10.1126/scisignal.aba7823
Frohner, I. E., Mudrak, I., Kronlachner, S., Schüchner, S. & Ogris, E. Antibodies recognizing the C terminus of PP2A catalytic subunit are unsuitable for evaluating PP2A activity and holoenzyme composition. Sci. Signal. 13, eaax6490 (2020).
pubmed: 31992581 doi: 10.1126/scisignal.aax6490
Couzens, A. L. et al. Protein interaction network of the mammalian Hippo pathway reveals mechanisms of kinase-phosphatase interactions.Sci. Signal. 6, rs15 (2013).
pubmed: 24255178 doi: 10.1126/scisignal.2004712
St-Denis, N. et al. Phenotypic and interaction profiling of the human phosphatases identifies diverse mitotic regulators. Cell Rep. 17, 2488–2501 (2016).
pubmed: 27880917 doi: 10.1016/j.celrep.2016.10.078
Yadav, L. et al. Systematic analysis of human protein phosphatase interactions and dynamics. Cell Syst. 4, 430–444 e5 (2017).
pubmed: 28330616 doi: 10.1016/j.cels.2017.02.011
Heroes, E. et al. The PP1 binding code: a molecular-lego strategy that governs specificity. FEBS J. 280, 584–595 (2013).
pubmed: 22360570 doi: 10.1111/j.1742-4658.2012.08547.x
Swingle, M., Ni, L. & Honkanen, R. E. Small-molecule inhibitors of ser/thr protein phosphatases: Specificity, use and common forms of abuse. Methods Mol. Biol. 365, 23–38 (2007).
pubmed: 17200551 pmcid: 2709456
Moorhead, G. B. G., Haystead, T. A. J. & MacKintosh, C. Synthesis and use of the protein phosphatase affinity matrices microcystin-sepharose and microcystin-biotin-sepharose. Methods Mol. Biol. 365, 39–45 (2007).
pubmed: 17200552
Duncan, J. S. et al. Dynamic reprogramming of the kinome in response to targeted MEK inhibition in triple-negative breast cancer. Cell 149, 307–321 (2012).
pubmed: 22500798 pmcid: 3328787 doi: 10.1016/j.cell.2012.02.053
Godl, K. et al. An efficient proteomics method to identify the cellular targets of protein kinase inhibitors. Proc. Natl Acad. Sci. USA 100, 15434–15444 (2003).
pubmed: 14668439 pmcid: 307585 doi: 10.1073/pnas.2535024100
Bantscheff, M. et al. Quantitative chemical proteomics reveals mechanisms of action of clinical ABL kinase inhibitors. Nat. Biotechnol. 25, 1035–1044 (2007).
pubmed: 17721511 doi: 10.1038/nbt1328
Kruse, U. et al. Chemoproteomics-based kinome profiling and target deconvolution of clinical multi-kinase inhibitors in primary chronic lymphocytic leukemia cells. Leukemia 25, 89–100 (2011).
pubmed: 20944678 doi: 10.1038/leu.2010.233
Midland, A. A. et al. Defining the expressed breast cancer kinome. Cell Res. 22, 620–623 (2012).
pubmed: 22310242 pmcid: 3317564 doi: 10.1038/cr.2012.25
Stuhlmiller, T. J. et al. Inhibition of lapatinib-induced kinome reprogramming in ERBB2-positive breast cancer by targeting BET family bromodomains. Cell Rep. 11, 390–404 (2015).
pubmed: 25865888 pmcid: 4408261 doi: 10.1016/j.celrep.2015.03.037
Cooper, M. J. et al. Application of multiplexed kinase inhibitor beads to study kinome adaptations in drug-resistant leukemia. PLoS One 8, e66755 (2013).
pubmed: 23826126 pmcid: 3691232 doi: 10.1371/journal.pone.0066755
Johnson, G. L., Stuhlmiller, T. J., Angus, S. P., Zawistowski, J. S. & Graves, L. M. Molecular pathways: adaptive kinome reprogramming in response to targeted inhibition of the BRAF-MEK-ERK pathway in cancer. Clin. Cancer Res. 20, 2516–2522 (2014).
pubmed: 24664307 pmcid: 4024346 doi: 10.1158/1078-0432.CCR-13-1081
Klaeger, S. et al. The target landscape of clinical kinase drugs. Science 358, eaan4368 (2017).
pubmed: 29191878 pmcid: 6542668 doi: 10.1126/science.aan4368
Hughes, P. F. et al. A highly selective Hsp90 affinity chromatography resin with a cleavable linker. Bioorganic Med. Chem. 20, 3298–3305 (2012).
doi: 10.1016/j.bmc.2012.03.043
Ranjitkar, P., Brock, A. M. & Maly, D. J. Affinity reagents that target a specific inactive form of protein kinases. Chem. Biol. 17, 195–206 (2010).
pubmed: 20189109 pmcid: 2871157 doi: 10.1016/j.chembiol.2010.01.008
Moorhead, G., MacKintosh, R. W., Morrice, N., Gallagher, T. & MacKintosh, C. Purification of type 1 protein (serine/threonine) phosphatases by microcystin-Sepharose affinity chromatography. FEBS Lett 356, 46–50 (1994).
pubmed: 7988718 doi: 10.1016/0014-5793(94)01232-6
Hughes, C. S. et al. Single-pot, solid-phase-enhanced sample preparation for proteomics experiments. Nat. Protoc. 14, 68–85 (2019).
pubmed: 30464214 doi: 10.1038/s41596-018-0082-x
Ting, L., Rad, R., Gygi, S. P. & Haas, W. MS3 eliminates ratio distortion in isobaric multiplexed quantitative proteomics. Nat. Methods 8, 937–940 (2011).
pubmed: 21963607 pmcid: 3205343 doi: 10.1038/nmeth.1714
Eng, J. K., Jahan, T. A. & Hoopmann, M. R. Comet: an open-source MS/MS sequence database search tool. Proteomics 13, 22–24 (2013).
pubmed: 23148064 doi: 10.1002/pmic.201200439
Valot, B., Langella, O., Nano, E. & Zivy, M. MassChroQ: a versatile tool for mass spectrometry quantification. Proteomics 11, 3572–3577 (2011).
pubmed: 21751374 doi: 10.1002/pmic.201100120
R Core Team. The R Project for Statistical Computing. https://www.R-project.org/ (2019).
Tyanova, S. et al. The Perseus computational platform for comprehensive analysis of (prote)omics data. Nat. Methods 13, 731–740 (2016).
pubmed: 27348712 doi: 10.1038/nmeth.3901
Yu, S. H. et al. Expanding the Perseus software for omics data analysis with custom plugins. Curr. Protoc. Bioinformatics 71, 1–29 (2020).
doi: 10.1002/cpbi.105
Johnson, W. E., Li, C. & Rabinovic, A. Adjusting batch effects in microarray expression data using empirical Bayes methods. Biostatistics 8, 118–127 (2007).
pubmed: 16632515 doi: 10.1093/biostatistics/kxj037
Rappsilber, J., Mann, M. & Ishihama, Y. Protocol for micro-purification, enrichment, pre-fractionation and storage of peptides for proteomics using StageTips. Nat. Protoc. 2, 1896–1906 (2007).
pubmed: 17703201 doi: 10.1038/nprot.2007.261
Zecha, J. et al. TMT labeling for the masses: a robust and cost-efficient, in-solution labeling approach. Mol. Cell Proteomics 18, 1468–1478 (2019).
pubmed: 30967486 pmcid: 6601210 doi: 10.1074/mcp.TIR119.001385
Kettenbach, A. N. & Gerber, S. A. Rapid and reproducible single-stage phosphopeptide enrichment of complex peptide mixtures: application to general and phosphotyrosine-specific phosphoproteomics experiments. Anal. Chem. 83, 7635–7644 (2011).
pubmed: 21899308 pmcid: 3251014 doi: 10.1021/ac201894j
Bollen, M., Peti, W., Ragusa, M. J. & Beullens, M. The extended PP1 toolkit: designed to create specificity. Trends Biochem. Sci. 35, 450–458 (2010).
pubmed: 20399103 pmcid: 3131691 doi: 10.1016/j.tibs.2010.03.002
Nilsson, J. Protein phosphatases in the regulation of mitosis. J. Cell Biol. 218, 395–409 (2019).
pubmed: 30446607 pmcid: 6363451 doi: 10.1083/jcb.201809138
Krystkowiak, I. & Davey, N. E. SLiMSearch: a framework for proteome-wide discovery and annotation of functional modules in intrinsically disordered regions. Nucleic Acids Res. 45, W464–W469 (2017).
pubmed: 28387819 pmcid: 5570202 doi: 10.1093/nar/gkx238
Chen, M. J., Dixon, J. E. & Manning, G. Genomics and evolution of protein phosphatases. Sci. Signal. 10, eaag1796 (2017).
pubmed: 28400531 doi: 10.1126/scisignal.aag1796
Uhlen, M. et al. Tissue-based map of the human proteome. Science 347, 1260419–1260419 (2015).
pubmed: 25613900 doi: 10.1126/science.1260419
Nusinow, D. P. et al. Quantitative proteomics of the Cancer Cell Line Encyclopedia. Cell 180, 387–402 (2020).
pubmed: 31978347 pmcid: 7339254 doi: 10.1016/j.cell.2019.12.023
Wang, D. et al. A deep proteome and transcriptome abundance atlas of 29 healthy human tissues. Mol. Syst. Biol. 15, e8503 (2019).
pubmed: 30777892 pmcid: 6379049 doi: 10.15252/msb.20188503
Xu, Y. et al. Structure of the protein phosphatase 2A holoenzyme. Cell 127, 1239–1251 (2006).
pubmed: 17174897 doi: 10.1016/j.cell.2006.11.033
Cho, U. S. & Xu, W. Crystal structure of a protein phosphatase 2A heterotrimeric holoenzyme. Nature 445, 53–57 (2007).
pubmed: 17086192 doi: 10.1038/nature05351
Seshacharyulu, P., Pandey, P., Datta, K. & Batra, S. K. Phosphatase: PP2A structural importance, regulation and its aberrant expression in cancer. Cancer Lett. 335, 9–18 (2013).
pubmed: 23454242 pmcid: 3665613 doi: 10.1016/j.canlet.2013.02.036
da Cruz e Silva, E. F. & Cohen, P. T. Isolation of a cDNA likely to encode a novel Ca2+-dependent/calmodulin-stimulated protein phosphatase. Biochim. Biophys. Acta 1009, 293–296 (1989).
pubmed: 2557079 doi: 10.1016/0167-4781(89)90118-8
Klee, C. B., Ren, H. & Wang, X. Regulation of the calmodulin-stimulated protein phosphatase, calcineurin. J. Biol. Chem. 273, 13367–13370 (1998).
pubmed: 9593662 doi: 10.1074/jbc.273.22.13367
Rusnak, F. & Mertz, P. Calcineurin: form and function. Physiol. Rev. 80, 1483–1521 (2000).
pubmed: 11015619 doi: 10.1152/physrev.2000.80.4.1483
Li, H., Rao, A. & Hogan, P. G. Interaction of calcineurin with substrates and targeting proteins. Trends Cell Biol. 21, 91–103 (2011).
pubmed: 21115349 doi: 10.1016/j.tcb.2010.09.011
Gingras, A. C. et al. A novel, evolutionarily conserved protein phosphatase complex involved in cisplatin sensitivity. Mol. Cell Proteomics 4, 1725–1740 (2005).
pubmed: 16085932 doi: 10.1074/mcp.M500231-MCP200
Kloeker, S. & Wadzinski, B. E. Purification and identification of a novel subunit of protein serine/threonine phosphatase 4. J. Biol. Chem. 274, 5339–5347 (1999).
pubmed: 10026142 doi: 10.1074/jbc.274.9.5339
Chen, M. X. et al. A novel human protein serine/threonine phosphatase, which possesses four tetratricopeptide repeat motifs and localizes to the nucleus. EMBO J. 13, 4278–4290 (1994).
pubmed: 7925273 pmcid: 395355 doi: 10.1002/j.1460-2075.1994.tb06748.x
Das, A. K., Cohen, P. W. & Barford, D. The structure of the tetratricopeptide repeats of protein phosphatase 5: implications for TPR-mediated protein-protein interactions. EMBO J. 17, 1192–1199 (1998).
pubmed: 9482716 pmcid: 1170467 doi: 10.1093/emboj/17.5.1192
Guergnon, J., Derewenda, U., Edelson, J. R. & Brautigan, D. L. Mapping of protein phosphatase-6 association with its SAPS domain regulatory subunit using a model of helical repeats. BMC Biochem. 10, 24 (2009).
pubmed: 19835610 pmcid: 2765987 doi: 10.1186/1471-2091-10-24
Stefansson, B., Ohama, T., Daugherty, A. E. & Brautigan, D. L. Protein phosphatase 6 regulatory subunits composed of ankyrin repeat domains. Biochemistry 47, 1442–1451 (2008).
pubmed: 18186651 doi: 10.1021/bi7022877
Huang, X. & Honkanen, R. E. Molecular cloning, expression, and characterization of a novel human serine/threonine protein phosphatase, PP7, that is homologous to Drosophila retinal degeneration C gene product (rdgC). J. Biol. Chem. 273, 1462–1468 (1998).
pubmed: 9430683 doi: 10.1074/jbc.273.3.1462
Verbinnen, I., Ferreira, M. & Bollen, M. Biogenesis and activity regulation of protein phosphatase 1. Biochem. Soc. Trans. 45, 89–99 (2017).
pubmed: 28202662 doi: 10.1042/BST20160154
Hertz, E. P. T. et al. A conserved motif provides binding specificity to the PP2A-B56 phosphatase. Mol. Cell 63, 686–695 (2016).
pubmed: 27453045 doi: 10.1016/j.molcel.2016.06.024
Wang, X., Bajaj, R., Bollen, M., Peti, W. & Page, R. Expanding the PP2A interactome by defining a B56-specific SLiM. Structure 24, 2174–2181 (2016).
pubmed: 27998540 pmcid: 5180209 doi: 10.1016/j.str.2016.09.010
Roy, J. & Cyert, M. S. Cracking the phosphatase code: docking interactions determine substrate specificity. Sci. Signal. 2, re9 (2009).
pubmed: 19996458 doi: 10.1126/scisignal.2100re9
Roy, J., Li, H., Hogan, P. G. & Cyert, M. S. A conserved docking site modulates substrate affinity for calcineurin, signaling output, and in vivo function. Mol. Cell 25, 889–901 (2007).
pubmed: 17386265 pmcid: 2913616 doi: 10.1016/j.molcel.2007.02.014
Ueki, Y. et al. A consensus binding motif for the PP4 protein phosphatase. Mol. Cell 76, 953–964 (2019).
pubmed: 31585692 pmcid: 6981294 doi: 10.1016/j.molcel.2019.08.029

Auteurs

Brooke L Brauer (BL)

Department of Biochemistry and Cell Biology, Geisel School of Medicine at Dartmouth, Hanover, NH, USA.

Kwame Wiredu (K)

Department of Molecular and Systems Biology, Geisel School of Medicine at Dartmouth, Hanover, NH, USA.

Sierra Mitchell (S)

Department of Biological Sciences, University of Calgary, Calgary, Alberta, Canada.

Greg B Moorhead (GB)

Department of Biological Sciences, University of Calgary, Calgary, Alberta, Canada.

Scott A Gerber (SA)

Department of Biochemistry and Cell Biology, Geisel School of Medicine at Dartmouth, Hanover, NH, USA.
Department of Molecular and Systems Biology, Geisel School of Medicine at Dartmouth, Hanover, NH, USA.
Norris Cotton Cancer Center, Geisel School of Medicine at Dartmouth, Lebanon, NH, USA.

Arminja N Kettenbach (AN)

Department of Biochemistry and Cell Biology, Geisel School of Medicine at Dartmouth, Hanover, NH, USA. Arminja.N.Kettenbach@dartmouth.edu.
Norris Cotton Cancer Center, Geisel School of Medicine at Dartmouth, Lebanon, NH, USA. Arminja.N.Kettenbach@dartmouth.edu.

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