Defect-Rich Hierarchical Porous UiO-66(Zr) for Tunable Phosphate Removal.

Adsorption Metal-Organic Frameworks Phosphates Porosity
defect chemistry hierarchical pores metal−organic frameworks monocarboxylic acids phosphate removal

Journal

Environmental science & technology
ISSN: 1520-5851
Titre abrégé: Environ Sci Technol
Pays: United States
ID NLM: 0213155

Informations de publication

Date de publication:
05 10 2021
Historique:
pubmed: 24 9 2021
medline: 16 10 2021
entrez: 23 9 2021
Statut: ppublish

Résumé

The introduction of defects into hierarchical porous metal-organic frameworks (HP-MOFs) is of vital significance to boost their adsorption performance. Herein, an advanced template-assisted strategy has been developed to fine-tune the phosphate adsorption performance of HP-MOFs by dictating the type and number of defects in HP-UiO-66(Zr). To achieve this, monocarboxylic acids of varying chain lengths have been employed as template molecules to fabricate an array of defect-rich HP-UiO-66(Zr) derivatives following removal of the template. The as-prepared HP-UiO-66(Zr) exhibits a higher sorption capacity and faster sorption rate compared to the pristine UiO-66(Zr). Particularly, the octanoic acid-modulated UiO-66(Zr) exhibits a high adsorption capacity of 186.6 mg P/g and an intraparticle diffusion rate of 6.19 mg/g·min

Identifiants

DOI: 10.1021/acs.est.1c01723 PMID: 34553909
pubmed: 34553909
doi: 10.1021/acs.est.1c01723
doi:

Substances chimiques

Metal-Organic Frameworks 0
Phosphates 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

13209-13218

Auteurs

Mohua Li (M)

Textile Pollution Controlling Engineering Center of Ministry of Environmental Protection, College of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China.

Yanbiao Liu (Y)

Textile Pollution Controlling Engineering Center of Ministry of Environmental Protection, College of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China.
ORCID: 0000-0001-8404-3806

Fang Li (F)

Textile Pollution Controlling Engineering Center of Ministry of Environmental Protection, College of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China.

Chensi Shen (C)

Textile Pollution Controlling Engineering Center of Ministry of Environmental Protection, College of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai 201620, China.
ORCID: 0000-0003-4459-566X

Yusuf Valentino Kaneti (YV)

Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, Queensland 4072, Australia.
ORCID: 0000-0003-2433-7305

Yusuke Yamauchi (Y)

Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, Queensland 4072, Australia.
JST-ERATO Yamauchi Materials Space-Tectonics Project and International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Tsukuba, Ibaraki 305-0044, Japan.
ORCID: 0000-0001-7854-927X

Brian Yuliarto (B)

Advanced Functional Materials Laboratory, Department of Engineering Physics, Institute of Technology Bandung, Bandung 40132, Indonesia.
Research Center for Nanosciences and Nanotechnology (RCNN), Institute of Technology Bandung, Bandung 40132, Indonesia.
ORCID: 0000-0003-0662-7923

Bo Chen (B)

Department of Chemistry, City University of Hong Kong, Hong Kong 999077 China.
ORCID: 0000-0001-6743-9251

Chong-Chen Wang (CC)

Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Beijing University of Civil Engineering and Architecture, Beijing 100044, China.
ORCID: 0000-0001-6033-7076

Articles similaires

Kinetic and thermodynamic analysis of alizarin Red S biosorption by Alhagi maurorum: a sustainable approach for water treatment.

Bushra Akram, Aisha Umar, M Ajmal Ali et al.
1.00
Anthraquinones Kinetics Water Purification Adsorption Thermodynamics

Removal mechanisms of pentachlorophenol in a horizontal-flow anaerobic immobilized biomass reactor (HAIB) inoculated with an indigenous estuarine sediment microbiota: adsorption and biodegradation processes.

Gunther Brucha, Alessandra Giordani, Bárbara Franco Vieira et al.
1.00
Pentachlorophenol Biodegradation, Environmental Bioreactors Adsorption Anaerobiosis

Structural optimization, characterization, and evaluation of binding mechanism of aptamers against bovine pregnancy-associated glycoproteins and their application in establishment of a colorimetric aptasensor using Fe-based metal-organic framework as peroxidase mimic tags.

Chunxia Lu, Jiaxiang Qin, Shijia Wu et al.
1.00
Aptamers, Nucleotide Cattle Animals Colorimetry Metal-Organic Frameworks

A phosphate starvation induced small RNA promotes Bacillus biofilm formation.

Yulong Li, Xianming Cao, Yunrong Chai et al.
1.00
Biofilms Gene Expression Regulation, Bacterial Bacillus Phosphates Bacterial Proteins

Classifications MeSH

questionsmedicales.fr › Phénomènes chimiques › Adsorption › Defect-Rich Hierarchical Porous UiO-66(Zr) for...
questionsmedicales.fr › Structures macromoléculaires › Réseaux organométalliques › Defect-Rich Hierarchical Porous UiO-66(Zr) for...
questionsmedicales.fr › Produits chimiques inorganiques › Composés du phosphore › Acides du phosphore › Acides phosphoriques › Phosphates › Defect-Rich Hierarchical Porous UiO-66(Zr) for...
questionsmedicales.fr › Phénomènes physiques › Phénomènes mécaniques › Porosité › Defect-Rich Hierarchical Porous UiO-66(Zr) for...