A shared mechanistic pathway for pyridoxal phosphate-dependent arginine oxidases.


Journal

Proceedings of the National Academy of Sciences of the United States of America
ISSN: 1091-6490
Titre abrégé: Proc Natl Acad Sci U S A
Pays: United States
ID NLM: 7505876

Informations de publication

Date de publication:
05 10 2021
Historique:
accepted: 21 07 2021
entrez: 28 9 2021
pubmed: 29 9 2021
medline: 15 12 2021
Statut: ppublish

Résumé

The mechanism by which molecular oxygen is activated by the organic cofactor pyridoxal phosphate (PLP) for oxidation reactions remains poorly understood. Recent work has identified arginine oxidases that catalyze desaturation or hydroxylation reactions. Here, we investigate a desaturase from the

Identifiants

pubmed: 34580201
pii: 2012591118
doi: 10.1073/pnas.2012591118
pmc: PMC8501904
pii:
doi:

Substances chimiques

Pyridoxal Phosphate 5V5IOJ8338
Mixed Function Oxygenases EC 1.-
Amino Acid Oxidoreductases EC 1.4.-
arginine oxidase EC 1.4.3.-

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : NIGMS NIH HHS
ID : R01 GM124480
Pays : United States

Déclaration de conflit d'intérêts

The authors declare no competing interest.

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Auteurs

Elesha R Hoffarth (ER)

Department of Chemistry, The University of British Columbia, Vancouver, BC V6T 1Z1, Canada.

Kersti Caddell Haatveit (K)

Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA 90095.

Eugene Kuatsjah (E)

Department of Microbiology and Immunology, The University of British Columbia, Vancouver, BC V6T 1Z3, Canada.

Gregory A MacNeil (GA)

Department of Chemistry, Simon Fraser University, Burnaby, BC V5A 1S6, Canada.

Simran Saroya (S)

Department of Chemistry, The University of British Columbia, Vancouver, BC V6T 1Z1, Canada.

Charles J Walsby (CJ)

Department of Chemistry, Simon Fraser University, Burnaby, BC V5A 1S6, Canada.

Lindsay D Eltis (LD)

Department of Microbiology and Immunology, The University of British Columbia, Vancouver, BC V6T 1Z3, Canada.

K N Houk (KN)

Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA 90095.

Marc Garcia-Borràs (M)

Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA 90095.
Institute of Computational Chemistry and Catalysis, University of Girona, 17003 Girona, Spain.
Department of Chemistry, University of Girona, 17003 Girona, Spain.

Katherine S Ryan (KS)

Department of Chemistry, The University of British Columbia, Vancouver, BC V6T 1Z1, Canada; ksryan@chem.ubc.ca.

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Classifications MeSH