Nitrite/Nitrous Acid Generation from the Reaction of Nitrate and Fe(II) Promoted by Photolysis of Iron-Organic Complexes.

Gaseous nitrous acid (HONO) has the potential to greatly contribute to the atmospheric oxidation capacity. Increased attention has been paid to in-particle nitrite or nitrous acid, N(III), as one of the HONO sources. However, sources and formation mechanisms of N(III) remain uncertain. Here, we study a much less examined reaction of Fe(II) and nitrate as a source of N(III). The N(III) production was indirectly probed by its multiphase reaction with SO