A zirconium metal-organic framework with SOC topological net for catalytic peptide bond hydrolysis.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
11 03 2022
Historique:
received: 25 05 2021
accepted: 27 12 2021
entrez: 12 3 2022
pubmed: 13 3 2022
medline: 6 4 2022
Statut: epublish

Résumé

The discovery of nanozymes for selective fragmentation of proteins would boost the emerging areas of modern proteomics, however, the development of efficient and reusable artificial catalysts for peptide bond hydrolysis is challenging. Here we report the catalytic properties of a zirconium metal-organic framework, MIP-201, in promoting peptide bond hydrolysis in a simple dipeptide, as well as in horse-heart myoglobin (Mb) protein that consists of 153 amino acids. We demonstrate that MIP-201 features excellent catalytic activity and selectivity, good tolerance toward reaction conditions covering a wide range of pH values, and importantly, exceptional recycling ability associated with easy regeneration process. Taking into account the catalytic performance of MIP-201 and its other advantages such as 6-connected Zr

Identifiants

pubmed: 35277474
doi: 10.1038/s41467-022-28886-5
pii: 10.1038/s41467-022-28886-5
pmc: PMC8917178
doi:

Substances chimiques

Metal-Organic Frameworks 0
Peptides 0
Zirconium C6V6S92N3C

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

1284

Informations de copyright

© 2022. The Author(s).

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Auteurs

Sujing Wang (S)

Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL Université, Paris, France. sjwang4@ustc.edu.cn.
CAS Key Laboratory of Microscale Magnetic Resonance and Suzhou Institute for Advanced Research, University of Science and Technology of China, Hefei, China. sjwang4@ustc.edu.cn.

Hong Giang T Ly (HGT)

Laboratory of Bioinorganic Chemistry, Department of Chemistry, KU Leuven, Leuven, Belgium.
Department of Chemistry, College of Natural Sciences, Can Tho University, Can Tho, Vietnam.

Mohammad Wahiduzzaman (M)

ICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier, France.

Charlotte Simms (C)

Laboratory of Bioinorganic Chemistry, Department of Chemistry, KU Leuven, Leuven, Belgium.

Iurii Dovgaliuk (I)

Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL Université, Paris, France.

Antoine Tissot (A)

Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL Université, Paris, France.

Guillaume Maurin (G)

ICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier, France.

Tatjana N Parac-Vogt (TN)

Laboratory of Bioinorganic Chemistry, Department of Chemistry, KU Leuven, Leuven, Belgium. tatjana.vogt@kuleuven.be.

Christian Serre (C)

Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL Université, Paris, France. christian.serre@ens.psl.eu.

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Classifications MeSH