Relaxation optimized double acquisition (RODA) as an alternative for virtual decoupling of NMR spectra.
Dissolution DNP
Double acquisition
IPAP
Spin-state selection
TROSY
Virtual decoupling
Journal
Journal of magnetic resonance (San Diego, Calif. : 1997)
ISSN: 1096-0856
Titre abrégé: J Magn Reson
Pays: United States
ID NLM: 9707935
Informations de publication
Date de publication:
04 2022
04 2022
Historique:
received:
09
01
2022
accepted:
23
02
2022
pubmed:
16
3
2022
medline:
11
5
2022
entrez:
15
3
2022
Statut:
ppublish
Résumé
We introduce an alternative way for spin-state selection, RODA, which yields higher sensitivity for spin systems exhibiting a TROSY effect. With RODA, the TROSY component of a doublet is recorded twice using a double acquisition scheme. RODA works by simple addition of consecutive NMR signals, and does not require any special processing. Thus, this pulse sequence element can seamlessly be integrated into existing experiments. We demonstrate the broad applicability of RODA with several systems exhibiting a TROSY effect on
Identifiants
pubmed: 35290935
pii: S1090-7807(22)00035-0
doi: 10.1016/j.jmr.2022.107177
pii:
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
107177Informations de copyright
Copyright © 2022 The Authors. Published by Elsevier Inc. All rights reserved.
Déclaration de conflit d'intérêts
Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.