Visible light-induced functionalization of indazole and pyrazole: a recent update.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
05 Apr 2022
05 Apr 2022
Historique:
pubmed:
17
3
2022
medline:
7
4
2022
entrez:
16
3
2022
Statut:
epublish
Résumé
Indazole and pyrazole are renowned as a prodigious class of heterocycles having versatile uses in medicinal as well as industrial chemistry. Considering sustainable approaches, recently, photocatalysis has become an indispensable tool in organic chemistry due to its application for the activation of small molecules and the use of a clean energy source. In this review, we have highlighted the use of metal-based photocatalysts, organic photoredox catalysts, energy transfer photocatalysts and electron-donor-acceptor complexes in the functionalization of indazole and pyrazole. This perspective is arranged based on the types of functionalization reactions on indazole and pyrazole. A detailed discussion regarding the reaction mechanism of each reaction is given to provide a comprehensive guide to the reader. Finally, a summary of existing challenges and the future outlook towards the development of efficient photocatalytic methods for functionalization of these heterocycles is also presented.
Substances chimiques
Indazoles
0
Pyrazoles
0
pyrazole
3QD5KJZ7ZJ
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM