Polydimethylsiloxane/graphene oxide/β-cyclodextrin sponge as a solid-phase extraction sorbent coupled with gas chromatography-mass spectrometry for rapid adsorption and sensitive determination of lavender essential oil.
lavender essential oil
microwave-assisted extraction
multivariate statistical analysis
polydimethylsiloxane
Journal
Journal of separation science
ISSN: 1615-9314
Titre abrégé: J Sep Sci
Pays: Germany
ID NLM: 101088554
Informations de publication
Date de publication:
Jun 2022
Jun 2022
Historique:
revised:
18
03
2022
received:
22
12
2021
accepted:
25
03
2022
pubmed:
31
3
2022
medline:
11
6
2022
entrez:
30
3
2022
Statut:
ppublish
Résumé
An adsorbent polydimethylsiloxane/graphene oxide/β-cyclodextrin sponge, which possessed the merits of high surface area, chemical stability, environment friendly, and excellent extraction capacity, was successfully fabricated. Based on the advantages, a novel microwave-assisted headspace solid-phase extraction method for lavender essential oil using polydimethylsiloxane/graphene oxide/β-cyclodextrin sponge as adsorbents was developed in this study. Various experimental parameters were studied. The optimal extraction conditions were as follows: 1 mg/mL as dopamine solution concentration, graphene oxide dosages of 30 mg, microwave power of 700 W, microwave irradiation time of 10 min, and desorption solvent of n-hexane. Under the optimal extraction condition, linearities ranging from 10 to 800 ng were achieved for six representative compounds with a correlation coefficients value of >0.99. The intra-day and inter-day precisions were in the ranges of 0.40-1.56 and 0.67-2.56%, respectively. Finally, the proposed technique was applied to analyze essential oil constituents in 14 samples of three lavender varieties, and 48 compounds were identified. Lavender varieties were distinguished using principal component analysis and partial least squares discriminant analysis. The results showed that the method developed in this study is a novel, simple, and sensitive method for the determination of essential oil in complex plant samples.
Identifiants
pubmed: 35353450
doi: 10.1002/jssc.202101018
doi:
Substances chimiques
Dimethylpolysiloxanes
0
Oils, Volatile
0
beta-Cyclodextrins
0
graphene oxide
0
Graphite
7782-42-5
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1904-1917Subventions
Organisme : Natural Science Foundation of Xinjiang Uygur Autonomous Region
ID : 2020D01C032
Organisme : National Natural Science Foundation of China
ID : 21565024
Informations de copyright
© 2022 Wiley-VCH GmbH.
Références
Kıvrak Ş. Essential oil composition and antioxidant activities of eight cultivars of Lavender and Lavandin from western Anatolia. Ind Crop Prod. 2018;117:88-96.
Chen P, Liu B, Fu J. Study on the group effect relationship of antioxidant active components in essential oil of Xinjiang lavender. Chin Pharm. 2021;32:1460-5.
Zhu Y, Fu J, Liu B, Tang J, Zhao J. Rapid Differentiation of Three Lavender Varieties Grown in China by Static Headspace Coupled with Gas Chromatography-Mass Spectrometry. J Essent Oil Bear Pl. 2019;21:1423-35.
Ahmad N, Zuo Y, Lu X, Anwar F, Hameed S. Characterization of free and conjugated phenolic compounds in fruits of selected wild plants. Food Chem. 2016;190:80-9.
Stierlin E, Nicole F, Fernandez X, Michel T. Development of a headspace solid-phase microextraction gas chromatography-mass spectrometry method to study volatile organic compounds (VOCs) emitted by lavender roots. Chem Biodivers. 2019;16:e1900280.
Fu J, Zhu Y, Liu B, Tang J. Fe3O4 sphere-assisted microwave distillation coupled with ionic liquid-based HS-SDME followed by GC-MS for the rapid analysis of essential oil in dried lavender. Anal Methods. 2018;10:652-9.
Tong H, Yang S. Identification and analysis of lavender flowers by headspace solid phase microextraction gas chromatography and chemometrics. Int Pharm Res. 2020;47:1015-20.
Chen P, Liu X, Wang L, Wang C, Fu J. Weighing paper-assisted magnetic ionic liquid headspace single-drop microextraction using microwave distillation followed by gas chromatography-mass spectrometry for the determination of essential oil components in lavender. J Sep Sci. 2021;44:585-99.
Nie J, Teng Y-J, Li Z-G, Liu W-H, Lee M-R. Magnetic nanoparticles used in headspace extraction coupled with DSI-GC-IT/MS for analysis of VOCs in dry traditional Chinese medicine. Chin Chem Lett. 2016;27:178-84.
Fu J, Zhao J, Zhu Y, Tang J. Rapid analysis of the essential oil components in dried lavender by magnetic microsphere-assisted microwave distillation coupled with HS-SPME followed by GC-MS. Food Anal Methods. 2017;10:2373-82.
Pena-Pereira F, Marcinkowski Ł, Kloskowski A, Namieśnik J. Ionogel fibres of bis(trifluoromethanesulfonyl)imide anion-based ionic liquids for the headspace solid-phase microextraction of chlorinated organic pollutants. Analyst. 2015;140:7417-22.
Donovan AR, Adams CD, Ma Y, Stephan C, Eichholz T, Shi H. Detection of zinc oxide and cerium dioxide nanoparticles during drinking water treatment by rapid single particle ICP-MS methods. Anal Bioanal Chem. 2016;408:5137-45.
Zhang Y, Xie Y, Zhang C, Wu M, Feng S. Preparation of porous magnetic molecularly imprinted polymers for fast and specifically extracting trace norfloxacin residue in pork liver. J Sep Sci. 2020;43:478-85.
Liu X, Fu J, Wang L, Wang C. Polydimethylsiloxane/ZIF-8@GO sponge headspace solid-phase extraction followed by GC-MS for the analysis of lavender essential oil. Anal Biochem. 2021;622:114167.
Liu Y, Wang X, Feng S. Nonflammable and magnetic sponge decorated with polydimethylsiloxane brush for multitasking and highly efficient oil-water separation. Adv Funct Mater. 2019;29:1902488.
Chen X, Weibel JA, Garimella SV. Continuous oil-water separation using polydimethylsiloxane-functionalized melamine sponge. Ind Eng Chem Res. 2016;55:3596-602.
Liu L, Chen J, Zhang W, Fan M, Gong Z, Zhang J, Graphene oxide/polydimethylsiloxane composite sponge for removing Pb(ii) from water. RSC Adv. 2020;10:22492-9.
Ma Y, Wang J, Xu S, Feng S, Wang J. Ag2O/sodium alginate-reduced graphene oxide aerogel beads for efficient visible light driven photocatalysis. Appl Surf Sci. 2018;430:155-64.
Hao Y, Li Z, Chen C, Xu Z, Feng S. Polyethyleneimine/graphene multilayer film supported ferric cobalt modified electrode for high-performance sensing of L-cysteine. J Electrochem. 2019;166:B1408-14.
Li N, Chen J, Shi YP. Magnetic reduced graphene oxide functionalized with beta-cyclodextrin as magnetic solid-phase extraction adsorbents for the determination of phytohormones in tomatoes coupled with high performance liquid chromatography. J Chromatogr A. 2016;1441:24-33.
Sakulpaisan S, Vongsetskul T, Reamouppaturm S, Luangkachao J, Tantirungrotechai J, Tangboriboonrat P. Titania-functionalized graphene oxide for an efficient adsorptive removal of phosphate ions. J Environ Manage. 2016;167:99-104.
Akamine LA, Vargas Medina DA, Lancas FM. Magnetic solid-phase extraction of gingerols in ginger containing products. Talanta 2021;222:121683.
Senosy IA, Guo HM, Ouyang MN, Lu ZH, Yang ZH, Li JH, Magnetic solid-phase extraction based on nano-zeolite imidazolate framework-8-functionalized magnetic graphene oxide for the quantification of residual fungicides in water, honey and fruit juices. Food Chem. 2020;325:126944.
Fang H, Zhao Y, Zhang Y, Ren Y, Bai SL. Three-dimensional graphene foam-filled elastomer composites with high thermal and mechanical properties. ACS Appl Mater Interfaces. 2017;9:26447-59.
Wang C, Cheng L, Zhang L, Zuo Y. Graphene oxide based molecularly imprinted polymers modified with beta-cyclodextrin for selective extraction of di(2-ethylhexyl) phthalate in environmental waters. J Sep Sci. 2019;42:1248-56.
Cui X, Cao D, Djellabi R, Qiao M, Wang Y, Zhao S. Enhancement of Ni/NiO/graphitized carbon and β-Cyclodextrin/reduced graphene oxide for the electrochemical detection of norfloxacin in water sample. J Electroanal Chem. 2019;851:113407.
Chen J, Cao S, Zhu M, Xi C, Zhang L, Li X. Fabrication of a high selectivity magnetic solid phase extraction adsorbent based on beta-cyclodextrin and application for recognition of plant growth regulators. J Chromatogr A. 2018;1547:1-13.
Zheng H, Gao Y, Zhu K, Wang Q, Wakeel M, Wahid A. Investigation of the adsorption mechanisms of Pb(II) and 1-naphthol by beta-cyclodextrin modified graphene oxide nanosheets from aqueous solution. J Colloid Interface Sci. 2018;530:154-62.
Zhao X, Li L, Li B, Zhang J, Wang A. Durable superhydrophobic/ superoleophilic PDMS sponges and their applications in selective oil absorption and in plugging oil leakages. J Mater Chem A. 2014;2:18281-7.
Yu C, Lu J, Dai J, Dong Z, Lin X, Xing W. Bio-inspired fabrication of Ester-functionalized imprinted composite membrane for rapid and high-efficient recovery of lithium ion from seawater. J Colloid Interface Sci. 2020;572:340-53.
Pokajewicz K, Bialon M, Svydenko L, Fedin R, Hudz N. Chemical composition of the essential oil of the new cultivars of Lavandula angustifolia mill. bred in ukraine. Molecules. 2021;26:5681.
Hassanein HD, El-Gendy A, Saleh IA, Hendawy SF, Elmissiry MM, Omer EA. Profiling of essential oil chemical composition of some Lamiaceae species extracted using conventional and microwave-assisted hydrodistillation extraction methods via chemometrics tools. Flavour Fragr J. 2020;35:329-40.
Luu TD, Le NH, Ngo DAT, Zhao J, Raffaella M, Neil F. Comparison of chemical composition, antioxidant and antimicrobial activity of lavender (Lavandula angustifolia L.) essential oils extracted by supercritical CO2, hexane and hydrodistillation. Food Bioproc Tech. 2013;6:3481-9.
Hamza A, Zeliha Y. Ultrasound-assisted extraction of antioxidant phenolic compounds from Lavandula angustifolia flowers using natural deep eutectic solvents: An experimental design approach. Sustain Chem Pharm. 2021;22:10492-503.
Guo XY, Wang P. Aroma characteristics of lavender extract and essential oil from Lavandula angustifolia Mill. Molecules 2020;25:5541.