Cobalt Bromide-Catalyzed Negishi-Type Cross-Coupling of Amides.

Amides Bromides Catalysis Cobalt

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
15 04 2022
Historique:
pubmed: 6 4 2022
medline: 19 4 2022
entrez: 5 4 2022
Statut: ppublish

Résumé

Herein, we describe a novel Negishi-type cross-coupling of amides employing only cobalt bromide salt as the catalyst. This original reaction is highly tolerant to various glutarimide amides as well as organozinc coupling partners. These conditions also allow the performance of the cross-coupling reaction in an eco-compatible solvent such as ethyl acetate on a large scale.

Identifiants

DOI: 10.1021/acs.orglett.2c00940 PMID: 35380446
pubmed: 35380446
doi: 10.1021/acs.orglett.2c00940
doi:

Substances chimiques

Amides 0
Bromides 0
Cobalt 3G0H8C9362

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

2778-2782

Auteurs

Céline Dorval (C)

LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.

Oleh Stetsiuk (O)

LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
ORCID: 0000-0003-3269-7466

Sylvaine Gaillard (S)

LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.

Elodie Dubois (E)

LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.

Corinne Gosmini (C)

LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
ORCID: 0000-0002-1355-2301

Grégory Danoun (G)

LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
ORCID: 0000-0003-2646-0091

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Amides › Cobalt Bromide-Catalyzed Negishi-Type...
questionsmedicales.fr › Produits chimiques inorganiques › Électrolytes › Ions › Anions › Bromures › Cobalt Bromide-Catalyzed Negishi-Type...
questionsmedicales.fr › Phénomènes chimiques › Catalyse › Cobalt Bromide-Catalyzed Negishi-Type...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Cobalt › Cobalt Bromide-Catalyzed Negishi-Type...