Chemiluminescence based on UV-assisted persulfate activation for sensitive detection of triphenyl phosphate.

Triphenyl phosphate (TPHP), a typical kind of organophosphorus flame retardants (OPFRs) with aryl groups, has been recognized as an emerging contaminant that causes environmental and health hazards. It is a pervasive threat that can be frequently detected in the environment and living organisms. Hence, establishing an efficient analytical method for TPHP is an urgent issue. In this work, a heteropolyacid (HPA)-luminol chemiluminescence strategy coupled with UV-assisted persulfate (PS) activation was proposed for the sensitive and selective detection of TPHP. The UV-assisted PS oxidation pretreatment could decompose the water-insoluble TPHP into smaller orthophosphates, which were further converted into HPA with the subsequently introduced vanadium‑molybdenum acid. The formed HPA served as a catalyst to oxidize luminol, and strong chemiluminescence at 425 nm was generated immediately. Furthermore, the degradation process of TPHP and chemiluminescence mechanism were also investigated. The results demonstrated that some reactive oxygen radicals such as SO

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Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have influenced the work reported in this paper.