Flavanols from Tetrapleura tetraptera with cytotoxic activities.


Journal

Fitoterapia
ISSN: 1873-6971
Titre abrégé: Fitoterapia
Pays: Netherlands
ID NLM: 16930290R

Informations de publication

Date de publication:
Jul 2022
Historique:
received: 19 03 2022
revised: 04 05 2022
accepted: 04 05 2022
pubmed: 12 5 2022
medline: 22 6 2022
entrez: 11 5 2022
Statut: ppublish

Résumé

Tetrapleura tetraptera is a medicinal plant used in East and West Africa to treat inflammation and related diseases. From the stem bark of the plant, three previously undescribed flavan-3-ol derivatives named (2R,3S)-3,3',5',7-tetrahydroxy-4'-methoxyflavane (1), (2R,3S)-3',5',7-trihydroxy-4'-methoxyflavane-3-O-β-D-glucopyranoside (2), and (2R,3S,4S)-3,3',4,5',7-pentahydroxy-4'-methoxyflavane (3) were isolated with three known analogues. The structural elucidation of the compounds was performed based on NMR spectroscopy and HRMS data analyses. The absolute configurations around the stereogenic carbons were determined using Circular Dichroism (ECD) and density functional theory (DFT) calculations. The cytotoxicity of the isolated compounds was tested using resazurin reduction assay. Compound 1 was moderately active against both recalcitrant leukemia cell lines with IC

Identifiants

pubmed: 35545131
pii: S0367-326X(22)00084-3
doi: 10.1016/j.fitote.2022.105206
pii:
doi:

Substances chimiques

Antineoplastic Agents 0
Antineoplastic Agents, Phytogenic 0
Plant Extracts 0
Polyphenols 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

105206

Informations de copyright

Copyright © 2022 Elsevier B.V. All rights reserved.

Auteurs

Oguntimehin Samuel Ayoolu (OS)

Department of Pharmacognosy, University of Ibadan, Ibadan, Nigeria; Institute of Environmental Research (INFU), Department of Chemistry and Chemical Biology, TU Dortmund, Dortmund, Germany.

Omonike Oluyemisi Ogbole (OO)

Department of Pharmacognosy, University of Ibadan, Ibadan, Nigeria.

Edith Oriabure Ajaiyeoba (EO)

Department of Pharmacognosy, University of Ibadan, Ibadan, Nigeria. Electronic address: edajaiye@gmail.com.

Vaderament-A Nchiozem-Ngnitedem (VA)

Department of Chemistry, University of Nairobi, Nairobi, Kenya.

Taye B Demissie (TB)

Department of Chemistry, University of Botswana, Gaborone, Botswana.

Mohamed Elbadawi (M)

Department of Pharmaceutical Biology, Institute of Pharmaceutical and Biomedical Sciences, Johannes Gutenberg University, Mainz, Germany.

Thomas Efferth (T)

Department of Pharmaceutical Biology, Institute of Pharmaceutical and Biomedical Sciences, Johannes Gutenberg University, Mainz, Germany.

Kibrom Gebreheiwot Bedane (KG)

Department of Chemistry, Addis Ababa University, Addis Ababa, Ethiopia. Electronic address: kibrom.gebrehiwot@aau.edu.et.

Michael Spiteller (M)

Institute of Environmental Research (INFU), Department of Chemistry and Chemical Biology, TU Dortmund, Dortmund, Germany.

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Classifications MeSH