Photocatalyzed Functionalization of Alkenoic Acids in 3D-Printed Reactors.
3D-printed reactors
carboxylic acids
flow chemistry
photocatalysis
radical reactions
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
07 Sep 2022
07 Sep 2022
Historique:
revised:
08
06
2022
received:
09
05
2022
pubmed:
14
6
2022
medline:
11
9
2022
entrez:
13
6
2022
Statut:
ppublish
Résumé
The valorization of alkenoic acids possibly deriving from biomass (fumaric and citraconic acids) was carried out through conversion in important building blocks, such as γ-keto acids and succinic acid derivatives. The functionalization was carried out by addition onto the C=C double bond of radicals generated under photocatalyzed conditions from suitable hydrogen donors (mainly aldehydes) and by adopting a decatungstate salt as the photocatalyst. Syntheses were performed under batch (in a glass vessel) and flow (by using 3D-printed reactors) conditions. The design of the latter reactors allowed for an improved yield and productivity.
Identifiants
pubmed: 35695876
doi: 10.1002/cssc.202200898
pmc: PMC9543820
doi:
Substances chimiques
Aldehydes
0
Hydrogen
7YNJ3PO35Z
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202200898Subventions
Organisme : The Regional Operational Programme of the European Regional Development Fund
ID : 1175234
Organisme : University of Pavia
Organisme : The Regional Operational Programme of the European Regional Development Fund
Organisme : POR FESR 2014-2020 program
Organisme : DSF (Digital Smart Fluidics): Fluidica Digitale per le Scienze della Vita
ID : 1175234
Informations de copyright
© 2022 The Authors. ChemSusChem published by Wiley-VCH GmbH.
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