Decatungstate-Photocatalyzed Dearomative Hydroacylation of Indoles: Direct Synthesis of 2-Acylindolines.
dearomatization
decatungstate
hydroacylation
indole
photocatalysis
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
07 Oct 2022
07 Oct 2022
Historique:
received:
02
06
2022
pubmed:
10
7
2022
medline:
12
10
2022
entrez:
9
7
2022
Statut:
ppublish
Résumé
We report herein a convenient and scalable dearomative hydroacylation reaction of indoles. Employing readily available aldehydes as the acyl source and TBADT as an inexpensive direct HAT photocatalyst, a variety of indoles derivatives were converted into synthetically interesting 2-acylindolines in good to excellent yields as well as great diastereoselectivity under mild conditions. An asymmetric version of the reaction was successfully developed and an experimental mechanistic investigation was carried out in order to gain further insights on the assumed reaction pathway.
Identifiants
pubmed: 35809229
doi: 10.1002/chem.202201707
doi:
Substances chimiques
2-acylindoline
0
Aldehydes
0
Indoles
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201707Informations de copyright
© 2022 Wiley-VCH GmbH.
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