Block Copolymer Synthesis by a Sequential Addition Strategy from the Organocatalytic Group Transfer Polymerization of Methyl Methacrylate to the Ring-Opening Polymerization of Lactide.
block copolymers
group transfer polymerization
organic catalysis of polymerization
phosphazene base
ring-opening polymerization
Journal
Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239
Informations de publication
Date de publication:
Oct 2022
Oct 2022
Historique:
revised:
27
06
2022
received:
26
04
2022
pubmed:
23
7
2022
medline:
22
10
2022
entrez:
22
7
2022
Statut:
ppublish
Résumé
Sequential block copolymerization involving comonomers belonging to different classes, e.g., a vinyl-type monomer and a heterocycle, is a challenging task in macromolecular chemistry, as corresponding propagating species do not interconvert easily from one to the other by crossover reactions. Here, it is first evidenced that 1-methoxy 2-methyl 1-trimethylsilyloxypropene (MTS), i.e., a silyl ketene acetal (SKA)-containing initiator, can be used in presence of the P
Identifiants
pubmed: 35868609
doi: 10.1002/marc.202200395
doi:
Substances chimiques
dilactide
95-96-5
Methylmethacrylate
196OC77688
Acetals
0
Polymethyl Methacrylate
9011-14-7
Polymers
0
ketene
LEP3SM032A
Methacrylates
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2200395Subventions
Organisme : French Ministry of Education and Research and to the Agence Nationale de la Recherche (ANR) HCO_for_LLAC
ID : 18-CE07-0018-02
Informations de copyright
© 2022 The Authors. Macromolecular Rapid Communications published by Wiley-VCH GmbH.
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