Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes.
C–H functionalization
alkylation
azobenzenes
electrochemistry
thioxanthenes
xanthenes
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
04 Aug 2022
04 Aug 2022
Historique:
received:
16
07
2022
revised:
31
07
2022
accepted:
02
08
2022
entrez:
12
8
2022
pubmed:
13
8
2022
medline:
16
8
2022
Statut:
epublish
Résumé
Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in moderate to good yields.
Identifiants
pubmed: 35956916
pii: molecules27154967
doi: 10.3390/molecules27154967
pmc: PMC9370205
pii:
doi:
Substances chimiques
Azo Compounds
0
Xanthenes
0
azobenzene
F0U1H6UG5C
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : The Key Project of Provincial Natural Science Research Foundation of Anhui Universities, China
ID : KJ2020A1195
Organisme : The National Science Foundation of China
ID : 21772061
Organisme : The Open Project of State Key Laboratory of Chemistry and Molecular Engineering of Medicinal Resources
ID : CMEMR2021-B14
Organisme : the Laboratory Open Project of Huaibei Normal University
ID : 2021sykf014
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