Vitamin E functions by association with a novel binding site on the 67 kDa laminin receptor activating diacylglycerol kinase.


Journal

The Journal of nutritional biochemistry
ISSN: 1873-4847
Titre abrégé: J Nutr Biochem
Pays: United States
ID NLM: 9010081

Informations de publication

Date de publication:
12 2022
Historique:
received: 27 08 2021
revised: 27 03 2022
accepted: 16 07 2022
pubmed: 18 8 2022
medline: 2 11 2022
entrez: 17 8 2022
Statut: ppublish

Résumé

It is generally recognized that the main function of α-tocopherol (αToc), which is the most active form of vitamin E, is its antioxidant effect, while non-antioxidant effects have also been reported. We previously found that αToc ameliorates diabetic nephropathy via diacylglycerol kinase alpha (DGKα) activation in vivo, and the activation was not related to the antioxidant effect. However, the underlying mechanism of how αToc activates DGKα have been enigmatic. We report that the membrane-bound 67 kDa laminin receptor (67LR), which has previously been shown to serve as a receptor for epigallocatechin gallate (EGCG), also contains a novel binding site for vitamin E, and its association with Vitamin E mediates DGKα activation by αToc. We employed hydrogen-deuterium exchange mass spectrometry (HDX/MS) and molecular dynamics (MD) simulations to identify the specific binding site of αToc on the 67LR and discovered the conformation of the specific hydrophobic pocket that accommodates αToc. Also, HDX/MS and MD simulations demonstrated the detailed binding of EGCG to a water-exposed hydrophilic site on 67LR, while in contrast αToc binds to a distinct hydrophobic site. We demonstrated that 67LR triggers an important signaling pathway mediating non-antioxidant effects of αToc, such as DGKα activation. This is the first evidence demonstrating a membrane receptor for αToc and one of the underlying mechanisms of a non-antioxidant function for αToc.

Identifiants

pubmed: 35977663
pii: S0955-2863(22)00197-8
doi: 10.1016/j.jnutbio.2022.109129
pmc: PMC10243646
mid: NIHMS1892528
pii:
doi:

Substances chimiques

Diacylglycerol Kinase EC 2.7.1.107
Vitamin E 1406-18-4
Receptors, Laminin 0
Catechin 8R1V1STN48
alpha-Tocopherol H4N855PNZ1
Antioxidants 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, N.I.H., Extramural

Langues

eng

Sous-ensembles de citation

IM

Pagination

109129

Subventions

Organisme : NIGMS NIH HHS
ID : F32 GM020501
Pays : United States
Organisme : NIGMS NIH HHS
ID : R01 GM020501
Pays : United States
Organisme : NIGMS NIH HHS
ID : R35 GM139641
Pays : United States

Informations de copyright

Copyright © 2022. Published by Elsevier Inc.

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Auteurs

Daiki Hayashi (D)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan; Department of Pharmacology, and Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California, USA.

Varnavas D Mouchlis (VD)

Department of Pharmacology, and Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California, USA.

Seika Okamoto (S)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan.

Tomoka Namba (T)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan.

Liuqing Wang (L)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan.

Sheng Li (S)

Department of Medicine, University of California San Diego, La Jolla, California, USA.

Shuji Ueda (S)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan.

Minoru Yamanoue (M)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan.

Hirofumi Tachibana (H)

Division of Applied Biological Chemistry, Department of Bioscience and Biotechnology, Faculty of Agriculture, Kyushu University, Fukuoka, Japan.

Hiroyuki Arai (H)

Department of Health Chemistry, Graduate School of Pharmaceutical Sciences, University of Tokyo, Tokyo Japan.

Hitoshi Ashida (H)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan.

Edward A Dennis (EA)

Department of Pharmacology, and Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California, USA.

Yasuhito Shirai (Y)

Department of Applied Chemistry in Bioscience, Graduate School of Agricultural Science, Faculty of Agriculture, Kobe University, Kobe, Japan. Electronic address: shirai@kobe-u.ac.jp.

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