Bimetallic Aluminum- and Niobium-Doped MCM-41 for Efficient Conversion of Biomass-Derived 2-Methyltetrahydrofuran to Pentadienes.
2-Methyltetrahydrofuran
Cleavage of C−O Bond
Niobium Sites
Pentadienes
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
19 12 2022
19 12 2022
Historique:
received:
17
08
2022
pubmed:
15
10
2022
medline:
15
12
2022
entrez:
14
10
2022
Statut:
ppublish
Résumé
The production of conjugated C4-C5 dienes from biomass can enable the sustainable synthesis of many important polymers and liquid fuels. Here, we report the first example of bimetallic (Nb, Al)-atomically doped mesoporous silica, denoted as AlNb-MCM-41, which affords quantitative conversion of 2-methyltetrahydrofuran (2-MTHF) to pentadienes with a high selectivity of 91 %. The incorporation of Al
Identifiants
pubmed: 36240785
doi: 10.1002/anie.202212164
pmc: PMC10098840
doi:
Substances chimiques
Niobium
05175J654G
Aluminum
CPD4NFA903
Alkadienes
0
MCM-41
0
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202212164Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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