Preparation and Characterization of a Formally Ni

Ligands Oxidation-Reduction Coordination Complexes / chemistry

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
14 12 2022
Historique:
pubmed: 2 12 2022
medline: 16 12 2022
entrez: 1 12 2022
Statut: ppublish

Résumé

High-valent first-row transition-metal-oxo complexes are important intermediates in biologically and chemically relevant oxidative transformations of organic molecules and in the water splitting reaction in (artificial) photosynthesis. While high-valent Fe- and Mn-oxo complexes have been characterized in detail, much less is known about their analogues with late transition metals. In this study, we present the synthesis and detailed characterization of a unique mononuclear terminal Ni-O complex. This compound, [Ni(TAML)(O)(OH)]

Identifiants

DOI: 10.1021/jacs.2c10196 PMID: 36454200
pubmed: 36454200
doi: 10.1021/jacs.2c10196
doi:

Substances chimiques

Ligands 0
Coordination Complexes 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

22698-22712

Auteurs

Deepika G Karmalkar (DG)

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.

Virginia A Larson (VA)

Department of Chemistry and Department of Biophysics, University of Michigan, Ann Arbor, Michigan 48109-1055, United States.
ORCID: 0000-0002-7094-6286

Deesha D Malik (DD)

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.

Yong-Min Lee (YM)

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.
ORCID: 0000-0002-5553-1453

Mi Sook Seo (MS)

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.
ORCID: 0000-0003-3302-2508

Jin Kim (J)

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.

Dovydas Vasiliauskas (D)

Department of Chemistry, Trinity University, San Antonio, Texas 78212-7200, United States.

Jason Shearer (J)

Department of Chemistry, Trinity University, San Antonio, Texas 78212-7200, United States.
ORCID: 0000-0001-7469-7304

Nicolai Lehnert (N)

Department of Chemistry and Department of Biophysics, University of Michigan, Ann Arbor, Michigan 48109-1055, United States.
ORCID: 0000-0002-5221-5498

Wonwoo Nam (W)

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.
ORCID: 0000-0001-8592-4867

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Classifications MeSH

questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Produits chimiques de laboratoire › Ligands › Preparation and Characterization of a Formally Ni
questionsmedicales.fr › Métabolisme › Métabolisme énergétique › Oxydoréduction › Preparation and Characterization of a Formally Ni
questionsmedicales.fr › Composés chimiques organiques › Complexes de coordination › Preparation and Characterization of a Formally Ni