Photocatalytic Performance of Undoped and Al-Doped ZnO Nanoparticles in the Degradation of Rhodamine B under UV-Visible Light:The Role of Defects and Morphology.

Al-doped ZnO Rhodamine B ZnO green light-irradiation nanomaterials photocatalysis photoluminescence solid-state 27Al-NMR

Journal

International journal of molecular sciences
ISSN: 1422-0067
Titre abrégé: Int J Mol Sci
Pays: Switzerland
ID NLM: 101092791

Informations de publication

Date de publication:
07 Dec 2022
Historique:
received: 07 11 2022
revised: 02 12 2022
accepted: 05 12 2022
entrez: 23 12 2022
pubmed: 24 12 2022
medline: 27 12 2022
Statut: epublish

Résumé

Quasi-spherical undoped ZnO and Al-doped ZnO nanoparticles with different aluminum content, ranging from 0.5 to 5 at% of Al with respect to Zn, were synthesized. These nanoparticles were evaluated as photocatalysts in the photodegradation of the Rhodamine B (RhB) dye aqueous solution under UV-visible light irradiation. The undoped ZnO nanopowder annealed at 400 °C resulted in the highest degradation efficiency of ca. 81% after 4 h under green light irradiation (525 nm), in the presence of 5 mg of catalyst. The samples were characterized using ICP-OES, PXRD, TEM, FT-IR,

Identifiants

pubmed: 36555102
pii: ijms232415459
doi: 10.3390/ijms232415459
pmc: PMC9779551
pii:
doi:

Substances chimiques

Zinc Oxide SOI2LOH54Z
rhodamine B K7G5SCF8IL
Aluminum CPD4NFA903

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : Hasselt University
ID : Project R-9087
Organisme : University of Namur
ID : Project R-9087
Organisme : Research Foundation - Flanders
ID : project AUHL/15/2-GOH3816N

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Auteurs

Alessandra Piras (A)

Laboratory of Applied Materials Chemistry, Unit of Nanomaterials Chemistry, Chemistry Department, University of Namur, NISM, Rue de Bruxelles, 61, 5000 Namur, Belgium.
DESINe Group, Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.

Chiara Olla (C)

Department of Physics, University of Cagliari, Cittadella Universitaria, I-09042 Monserrato, Italy.

Gunter Reekmans (G)

Analytical and Circular Chemistry (ACC), Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.

An-Sofie Kelchtermans (AS)

DESINe Group, Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.
EnergyVille, Thor Park 8320, 3600 Genk, Belgium.

Dries De Sloovere (D)

DESINe Group, Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.
EnergyVille, Thor Park 8320, 3600 Genk, Belgium.
Imec, Division Imomec, Wetenschapspark 1, 3590 Diepenbeek, Belgium.

Ken Elen (K)

DESINe Group, Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.
EnergyVille, Thor Park 8320, 3600 Genk, Belgium.
Imec, Division Imomec, Wetenschapspark 1, 3590 Diepenbeek, Belgium.

Carlo Maria Carbonaro (CM)

Department of Physics, University of Cagliari, Cittadella Universitaria, I-09042 Monserrato, Italy.

Luca Fusaro (L)

Laboratory of Applied Materials Chemistry, Unit of Nanomaterials Chemistry, Chemistry Department, University of Namur, NISM, Rue de Bruxelles, 61, 5000 Namur, Belgium.

Peter Adriaensens (P)

Analytical and Circular Chemistry (ACC), Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.

An Hardy (A)

DESINe Group, Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.
EnergyVille, Thor Park 8320, 3600 Genk, Belgium.
Imec, Division Imomec, Wetenschapspark 1, 3590 Diepenbeek, Belgium.

Carmela Aprile (C)

Laboratory of Applied Materials Chemistry, Unit of Nanomaterials Chemistry, Chemistry Department, University of Namur, NISM, Rue de Bruxelles, 61, 5000 Namur, Belgium.

Marlies K Van Bael (MK)

DESINe Group, Institute for Materials Research (imo-imomec), Hasselt University, Agoralaan Building D, 3590 Diepenbeek, Belgium.
EnergyVille, Thor Park 8320, 3600 Genk, Belgium.
Imec, Division Imomec, Wetenschapspark 1, 3590 Diepenbeek, Belgium.

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