One-Step Synthesis of Biphasic, Cavity-forming Polymer Particles via Dispersion Copolymerization of Styrene and Sulfobetaine Methacrylate.
dispersion copolymerization
heterogeneous polymerization
polymer colloids
polyzwitterions
Journal
Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239
Informations de publication
Date de publication:
Apr 2023
Apr 2023
Historique:
received:
04
01
2023
medline:
7
4
2023
pubmed:
27
1
2023
entrez:
26
1
2023
Statut:
ppublish
Résumé
A one-step dispersion copolymerization technique is demonstrated to fabricate biphasic particles as an approach to streamline the production of particles with complex morphology. The model system studies a monomer feed of hydrophobic styrene and hydrophilic, zwitterionic sulfobetaine methacrylate (SBMA) in a water/isopropanol cosolvent mixture. The resulting particles have a core-shell morphology that can be transformed, simply by washing the particles with water, into particles with a single surface opening connected to an interior cavity. Results indicate that particle morphology is dependent on the presence of nanoscopic SBMA-rich aggregates in the initial reaction mixture to act as nucleation sites, forming an SBMA-rich core encased in a styrene-rich shell. Systematic study of the morphology evolution reveals that the difference in monomer solubility profile can be exploited to control compositional drift of the particle composition during copolymerization yielding copolymer with sufficiently different composition to form phase-separated particle morphology. When SBMA is replaced with various ionic comonomers, the cavity-forming morphology is observed when reaction conditions result in low solubility of the comonomer in the cosolvent mixture. Based on these results, design guidelines are developed that may be applied to a variety of systems requiring complex and responsive particles made from chemically distinct comonomer pairings.
Identifiants
pubmed: 36698325
doi: 10.1002/marc.202200873
doi:
Substances chimiques
Polymers
0
Styrene
44LJ2U959V
sulfobetaine
8CVU22OCJW
Methacrylates
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2200873Informations de copyright
© 2023 Wiley-VCH GmbH.
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