Longevity of coal waste for controlling cadmium-contaminated groundwater considering groundwater velocity.

Cadmium Coal waste Longevity Nonequilibrium reaction Permeable reactive barrier Pore water velocity

Journal

Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769

Informations de publication

Date de publication:
Apr 2023
Historique:
received: 10 10 2022
accepted: 20 01 2023
medline: 18 4 2023
pubmed: 23 2 2023
entrez: 22 2 2023
Statut: ppublish

Résumé

Coal waste composed of naturally occurring minerals is applicable as a reactive medium to permeable reactive barriers due to its reactivity to heavy metals. In this study, we evaluated the longevity of coal waste as PRB media to control heavy metal-contaminated groundwater considering variable groundwater velocity. Breakthrough experiments were conducted using coal waste-filled column by injecting artificial groundwater, 10 mg/L of cadmium solution. The artificial groundwater was fed to the column at different flow rates to mimic a wide range of porewater velocities in the saturated zone. The reaction between cadmium breakthrough curves was analyzed using a two-site nonequilibrium sorption model. The cadmium breakthrough curves showed a significant retardation, which increased with decreasing porewater velocity. The greater the retardation, the longer the longevity of coal waste could be expected. The greater retardation under a slower velocity environment was due to the higher fraction of equilibrium reaction. The nonequilibrium reaction parameters could be functionalized with respect to the porewater velocity. The simulation of contaminant transport using the reaction parameters could be used as a method to evaluate the longevity of the pollution-blocking material in an underground environment.

Identifiants

pubmed: 36808035
doi: 10.1007/s11356-023-25542-3
pii: 10.1007/s11356-023-25542-3
doi:

Substances chimiques

Cadmium 00BH33GNGH
Coal 0
Metals, Heavy 0
Water Pollutants, Chemical 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

51170-51179

Subventions

Organisme : Korea Ministry of Environment (KR)
ID : ARQ202101728001

Informations de copyright

© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.

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Auteurs

Jae-Hyun Kim (JH)

Department of Earth and Environmental Sciences, Korea University, 145, Anam-Ro, Seongbuk-Gu, Seoul, 02841, Republic of Korea.

Ho Yeon Kwak (HY)

Department of Earth and Environmental Sciences, Korea University, 145, Anam-Ro, Seongbuk-Gu, Seoul, 02841, Republic of Korea.

Eunjie Kwak (E)

Department of Earth and Environmental Sciences, Korea University, 145, Anam-Ro, Seongbuk-Gu, Seoul, 02841, Republic of Korea.

Bong-Ju Kim (BJ)

Korea Atomic Energy Research Institute, 111, Daedeok-Daero 989Beon-Gil, Yuseong-Gu, Daejeon, 34057, Republic of Korea.

Soonjae Lee (S)

Department of Earth and Environmental Sciences, Korea University, 145, Anam-Ro, Seongbuk-Gu, Seoul, 02841, Republic of Korea. soonjam@korea.ac.kr.

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