Kinetic Control via Binding Sites within the Confined Space of Metal Metalloporphyrin-Frameworks for Enhanced Shape-Selectivity Catalysis.
Heterogeneous Catalysis
Kinetic Control
Metal-Organic Framework
Porphyrin
Shape-Selectivity
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
26 Jun 2023
26 Jun 2023
Historique:
received:
25
03
2023
medline:
2
5
2023
pubmed:
2
5
2023
entrez:
2
5
2023
Statut:
ppublish
Résumé
One striking feature of enzyme is its controllable ability to trap substrates via synergistic or cooperative binding in the enzymatic pocket, which renders the shape-selectivity of product by the confined spatial environment. The success of shape-selective catalysis relies on the ability of enzyme to tune the thermodynamics and kinetics for chemical reactions. In emulation of enzyme's ability, we showcase herein a targeting strategy with the substrate being anchored on the internal pore wall of metal-organic frameworks (MOFs), taking full advantage of the sterically kinetic control to achieve shape-selectivity for the reactions. For this purpose, a series of binding site-accessible metal metalloporphyrin-frameworks (MMPFs) have been investigated to shed light on the nature of enzyme-mimic catalysis. They exhibit a different density of binding sites that are well arranged into the nanospace with corresponding distances of opposite binding sites. Such a structural specificity results in a facile switch in selectivity from an exclusive formation of the thermodynamically stable product to the kinetic product. Thus, the proposed targeting strategy, based on the combination of porous materials and binding events, paves a new way to develop highly efficient heterogeneous catalysts for shifting selectivity.
Identifiants
pubmed: 37130008
doi: 10.1002/anie.202304303
doi:
Substances chimiques
Metalloporphyrins
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202304303Subventions
Organisme : Welch Foundation
ID : B-0027
Organisme : Basic Energy Sciences
ID : DE-AC52-07NA27344
Organisme : Basic Energy Sciences
ID : DE-AC02-06CH11357
Organisme : Division of Chemistry
ID : CHE-1834750
Organisme : Division of Chemistry
ID : CHE-1531468
Organisme : King Saud University
ID : RSP2023R79
Organisme : Fuel Cell Technologies Program
ID : DE-AC52-07NA2734
Organisme : Hydrogen and Fuel Cell Technologies Office
ID : DE-AC04-94AL85000
Informations de copyright
© 2023 Wiley-VCH GmbH.
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