Analysis and subcellular distribution of organophosphate esters (OPEs) in rice tissues.

Ethyl hexyl diphenyl phosphate Mass spectrometry Oryza sativa Subcellular fractionation Triphenyl phosphate Tris(1,3-dichloro-2-propyl) phosphate Tris(2-chloroethyl) phosphate

Journal

Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769

Informations de publication

Date de publication:
Jun 2023
Historique:
received: 09 11 2022
accepted: 07 05 2023
medline: 26 6 2023
pubmed: 18 5 2023
entrez: 17 5 2023
Statut: ppublish

Résumé

Recent studies have identified the ability of plants to uptake and translocate organophosphate esters (OPEs) within cells. In response to the increasing interest in OPEs and their occurrence in paddy fields and rice, the current study aimed to present an effective and sensitive GC-MS based methodology for quantitative determination of 11 OPEs with octanol-water coefficients ranging from 1.6 to 10. Rice was sonicated with hexane and dichloromethane, and fractionated on two columns: one consisting of neutral alumina, and neutral silica, and the other consisting of graphitized carbon black. Method precision was validated using spiked rice (n = 30) and procedural blanks (n = 9). The mean recovery of matrix spikes for all target OPEs were within 78-110% with relative standard deviation lower than 25%, with a few exceptions. This method was applied to process the wild rice (O. sativa) in which tri-n-propyl phosphate was the dominant targeted OPE. The recoveries of surrogate standards were 81 ± 17% for d

Identifiants

pubmed: 37198367
doi: 10.1007/s11356-023-27564-3
pii: 10.1007/s11356-023-27564-3
doi:

Substances chimiques

Flame Retardants 0
Esters 0
tris(chloroethyl)phosphate 32IVO568B0
Organophosphates 0
Phosphates 0
Water 059QF0KO0R

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

74021-74030

Subventions

Organisme : National Natural Science Foundation of China
ID : 42077334
Organisme : National Natural Science Foundation of China
ID : U20A20109
Organisme : GDAS' Project of Science and Technology Development
ID : 2020GDASYL-20200101002
Organisme : GDAS' Project of Science and Technology Development
ID : 2022GDASZH-2022010105
Organisme : Department of Finance of Guangdong Province
ID : 2022-GD-6

Informations de copyright

© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.

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Auteurs

Zifei Qin (Z)

National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China, Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Institute of Eco-Environmental and Soil Sciences, Guangdong Academy of Sciences, Guangzhou, 510650, China.

Liang-Ying Liu (LY)

Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou, 511443, China.

William A Stubbings (WA)

School of Geography, Earth, and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK.

Shaorui Wang (S)

National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China, Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Institute of Eco-Environmental and Soil Sciences, Guangdong Academy of Sciences, Guangzhou, 510650, China. srwang@soil.gd.cn.

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