CuO Promotes the Formation of Halogenated Disinfection Byproducts during Chlorination via an Enhanced Oxidation Pathway.

Previous studies showed that cupric oxide (CuO) can enhance the formation of trihalomethanes (THMs), haloacetic acids, and bromate during chlorination of bromide-containing waters. In this study, the impact of CuO on the formation kinetics and mechanisms of halogenated disinfection byproducts (DBPs) during chlorination was investigated. CuO does not enhance the formation of DBPs (i.e., 1,1,1-trichloropropanone, chloroform, and trichloroacetaldehyde (TCAL) /dichloroacetonitrile) during chlorination of acetone, 3-oxopentanedioic acid (3-OPA), and aspartic acid, respectively. This indicates that the halogen substitution pathway cannot be enhanced by CuO. Instead, CuO (0.1 g L