Development of biobased multifunctional films incorporated with essential oils@polydopamine nanocapsules for food preservation applications.

A novel multifunctional soy protein isolate-carboxymethyl cellulose (SPI-CMC) based nanocomposite film was successfully prepared by introducing the polydopamine encapsulated essential oils (EOs@PDA) nanocapsules for food packaging. The EOs@PDA nanocapsules possessed smooth spherical morphology with good dispersion, and the particle size was about 283 nm. The influence of EOs@PDA nanocapsules on the physical, chemical and biological properties of EOs@PDA/SPI-CMC nanocomposite film was investigated. The EOs@PDA nanocapsules were crosslinked with SPI-CMC matrix and distributed uniformly in the matrix. The nanocomposite film with 1 wt% nanocapsules (EP/S-C) also showed excellent antioxidant activity (66.6 ± 0.3 % on DPPH and 98.6 ± 0.1 % on ABTS), superior UV-blocking properties (100 %), advanced antibacterial ability against E. coli and S. aureus, favorable biodegradability (>90 %) and relatively low In vitro cytotoxicity. Also, the EP/S-C nanocomposite film displayed potential to extend the shelf life of fresh cut apple slices (>24 h), perishable cherry tomatoes and blueberries (>6 days). The results suggested that the EOs@PDA/SPI-CMC nanocomposite film had a great possibility in the field of biodegradable and antimicrobial materials for food packaging.

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Declaration of competing interest All authors have seen and approved the final version of the manuscript being submitted. We confirm that the article is original and has not been published elsewhere, nor is it currently under consideration for publication elsewhere. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work in this paper.