Photo-enhanced oxidation of arsenite by biochar: The effect of pH, kinetics and mechanisms.

The persistent and photo-induced free radicals of biochar play significant roles in the transformation or degradation of inorganic and organic pollutants. However, the redox capacity of biochar for arsenite (As(III)) photochemistry under different pH conditions remains unclear. In this study, we discovered that solar radiation primarily expedited the oxidation of As(III) by biochar by augmenting the production of reactive oxygen species (ROS). Biochar demonstrated a strong pH reliance on the photooxidation of As(III). Under acidic and neutral conditions, solar radiation amplified the generation of •OH (hydroxyl radicals) by BC-P (phenolic -OH of biochar) and semiquinone-type BC-PFRs (persistent free radicals of biochar) by 4.9 and 2.0 times, respectively, resulting in enhanced As(III) oxidation. Under alkaline conditions, BC-P and BC-Q (quinoid CO of biochar) facilitated the production of H

Informations de copyright

Copyright © 2023 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare there no financial interests or personal relationships that could have appeared to influence the work reported in this paper.