Recent Advances in Palladium-Catalyzed [4 + n] Cycloaddition of Lactones, Benzoxazinanones, Allylic Carbonates, and Vinyloxetanes.

Cycloaddition Reaction Palladium Lactones Catalysis Carbonates
Allylation Palladium catalysis [4 + n] cycloaddition

Journal

Topics in current chemistry (Cham)
ISSN: 2364-8961
Titre abrégé: Top Curr Chem (Cham)
Pays: Switzerland
ID NLM: 101691301

Informations de publication

Date de publication:
03 Nov 2023
Historique:
received: 17 06 2023
accepted: 06 10 2023
medline: 6 11 2023
pubmed: 3 11 2023
entrez: 3 11 2023
Statut: epublish

Résumé

Palladium-catalyzed allylation cyclization reaction has recently emerged as an efficient and powerful synthetic platform for the construction of diverse and valuable carbo- and heterocycles. Thus the development of new allylic motifs for achieving this type of transformations in high reactivity and selectivity is of great importance. Generally, these substrates have been utilized as 1,3-, 1,4-, 1,5-, 1,6-dipoles in many reactions, which are applied to prepare highly functionalized products with complete control of chemo-, regio-, diastereo-, and enantioselectivity. In this review, we focus our attention on the development of palladium-catalyzed [4 + n] cycloaddition of allylic motifs and describe a comprehensive and impressive advances in this area. Meanwhile, the related mechanism and the application of these annulation strategies in natural product total synthesis will be highlighted in detail.

Identifiants

DOI: 10.1007/s41061-023-00442-9 PMID: 37921912
pubmed: 37921912
doi: 10.1007/s41061-023-00442-9
pii: 10.1007/s41061-023-00442-9
doi:

Substances chimiques

Palladium 5TWQ1V240M
Lactones 0
Carbonates 0

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

33

Subventions

Organisme : National Natural Science Foundation of China
ID : 21702189
Organisme : Key scientific and technological project of Henan Province
ID : 202102310004
Organisme : Science and technology research and development plan joint fund (cultivation of superior disciplines) project
ID : 222301420042
Organisme : Zhengzhou University
ID : JC21253007

Informations de copyright

© 2023. The Author(s), under exclusive licence to Springer Nature Switzerland AG.

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Auteurs

Mengyan Guo (M)

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, People's Republic of China.

Panke Zhang (P)

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, People's Republic of China. pkzhang@zzu.edu.cn.

Er-Qing Li (EQ)

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou, 450001, People's Republic of China. lierqing@zzu.edu.cn.
ORCID: 0000-0003-1286-6832

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Classifications MeSH

questionsmedicales.fr › Technologie, industrie et agriculture › Technologie › Technologie pharmaceutique › Techniques de chimie synthétique › Réaction de cycloaddition › Recent Advances in Palladium-Catalyzed [4 + n]...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Palladium › Recent Advances in Palladium-Catalyzed [4 + n]...
questionsmedicales.fr › Composés chimiques organiques › Lactones › Recent Advances in Palladium-Catalyzed [4 + n]...
questionsmedicales.fr › Phénomènes chimiques › Catalyse › Recent Advances in Palladium-Catalyzed [4 + n]...
questionsmedicales.fr › Produits chimiques inorganiques › Électrolytes › Ions › Anions › Carbonates › Recent Advances in Palladium-Catalyzed [4 + n]...