Synthesis of Sucrose-Mimicking Disaccharide by Intramolecular Aglycone Delivery.
allose
glycosylation
intramolecular aglycone delivery
psicose
rare sugar
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
13 Apr 2024
13 Apr 2024
Historique:
received:
08
02
2024
revised:
11
04
2024
accepted:
12
04
2024
medline:
27
4
2024
pubmed:
27
4
2024
entrez:
27
4
2024
Statut:
epublish
Résumé
Rare sugars are known for their ability to suppress postprandial blood glucose levels. Therefore, oligosaccharides and disaccharides derived from rare sugars could potentially serve as functional sweeteners. A disaccharide [α-d-allopyranosyl-(1→2)-β-d-psicofuranoside] mimicking sucrose was synthesized from rare monosaccharides D-allose and D-psicose. Glycosylation using the intermolecular aglycon delivery (IAD) method was employed to selectively form 1,2-
Identifiants
pubmed: 38675593
pii: molecules29081771
doi: 10.3390/molecules29081771
pii:
doi:
Substances chimiques
Disaccharides
0
Sucrose
57-50-1
Sweetening Agents
0
psicose
23140-52-5
allose
6038-51-3
Fructose
30237-26-4
Glucose
IY9XDZ35W2
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : Japan Society for the Promotion of Science
ID : JP22H02196
Organisme : Japan Society for the Promotion of Science
ID : JP21K05282
Organisme : Japan Society for the Promotion of Science
ID : JP16H06290
Organisme : Mizutani Foundation for Glycoscience
ID : research grants in 2023